Matches in SemOpenAlex for { <https://semopenalex.org/work/W4207064293> ?p ?o ?g. }
- W4207064293 abstract "Catalytic hydrogenolysis of biobased furan aldehydes (i. e., 5-methylfurfural, 5-hydroxymethylfurfural) to 2,5-dimethylfuran has gained extensive interest for biomass-derived fuels and chemicals. Herein, a class of NiCo2 O4 -supported palladium with considerable oxygen defects was synthesized by hydrogen plasma etching and phosphating methods. The oxygen defects not only promoted the hydrogenation of the C=O group but also enhanced the accessibility of coordinatively unsaturated metal cations with Lewis acidity for the hydrogenolysis of the C-OH group. Meanwhile, the additional Brønsted acidity in Pd/NiCo2 O4-x obtained by phosphating could further strengthen the hydrogenolysis ability by the etherification route of C-OH. Finally, Pd/NiCo2 O4-x exhibited the most effective performance with 2,5-dimethylfuran yields of 92.9 and 90.5 % from 5-methylfurfural and 5-hydroxymethylfurfural, respectively. These catalytic mechanisms were confirmed by in-situ infrared spectroscopy and control experiments. Furthermore, the catalyst showed outstanding recycling stability. This work shows powerful synergistic catalysis in the hydrogenolysis reaction by multifunctional active sites." @default.
- W4207064293 created "2022-01-26" @default.
- W4207064293 creator A5039783155 @default.
- W4207064293 creator A5042241049 @default.
- W4207064293 creator A5045152496 @default.
- W4207064293 creator A5048067331 @default.
- W4207064293 creator A5054030311 @default.
- W4207064293 creator A5080694348 @default.
- W4207064293 creator A5088019501 @default.
- W4207064293 date "2022-02-09" @default.
- W4207064293 modified "2023-10-18" @default.
- W4207064293 title "Promoted Hydrogenolysis of Furan Aldehydes to 2,5‐Dimethylfuran by Defect Engineering on Pd/NiCo <sub>2</sub> O <sub>4</sub>" @default.
- W4207064293 cites W1862914860 @default.
- W4207064293 cites W1896530895 @default.
- W4207064293 cites W1919942120 @default.
- W4207064293 cites W1984920634 @default.
- W4207064293 cites W1986423170 @default.
- W4207064293 cites W1994889174 @default.
- W4207064293 cites W2001739119 @default.
- W4207064293 cites W2008713954 @default.
- W4207064293 cites W2008941899 @default.
- W4207064293 cites W2013010023 @default.
- W4207064293 cites W2066192242 @default.
- W4207064293 cites W2072438113 @default.
- W4207064293 cites W2082409027 @default.
- W4207064293 cites W2084726128 @default.
- W4207064293 cites W2093387535 @default.
- W4207064293 cites W2097112788 @default.
- W4207064293 cites W2103099844 @default.
- W4207064293 cites W2111684517 @default.
- W4207064293 cites W2143228730 @default.
- W4207064293 cites W2143765146 @default.
- W4207064293 cites W2144742802 @default.
- W4207064293 cites W2169801839 @default.
- W4207064293 cites W2183694761 @default.
- W4207064293 cites W2332824798 @default.
- W4207064293 cites W2333741792 @default.
- W4207064293 cites W2411118723 @default.
- W4207064293 cites W2419635102 @default.
- W4207064293 cites W2470961612 @default.
- W4207064293 cites W2566301674 @default.
- W4207064293 cites W2581519452 @default.
- W4207064293 cites W2593010013 @default.
- W4207064293 cites W2598470986 @default.
- W4207064293 cites W2605372921 @default.
- W4207064293 cites W2618410885 @default.
- W4207064293 cites W2760884288 @default.
- W4207064293 cites W2766328401 @default.
- W4207064293 cites W2773425831 @default.
- W4207064293 cites W2775152481 @default.
- W4207064293 cites W2785311488 @default.
- W4207064293 cites W2790954641 @default.
- W4207064293 cites W2795116762 @default.
- W4207064293 cites W2803728123 @default.
- W4207064293 cites W2891706685 @default.
- W4207064293 cites W2915717640 @default.
- W4207064293 cites W2917641140 @default.
- W4207064293 cites W2920897049 @default.
- W4207064293 cites W2923939018 @default.
- W4207064293 cites W2942644445 @default.
- W4207064293 cites W2974494851 @default.
- W4207064293 cites W3005497553 @default.
- W4207064293 cites W3006049630 @default.
- W4207064293 cites W3008858027 @default.
- W4207064293 cites W3011656359 @default.
- W4207064293 cites W3021985021 @default.
- W4207064293 cites W3022880521 @default.
- W4207064293 cites W3034833349 @default.
- W4207064293 cites W3039296056 @default.
- W4207064293 cites W3047002598 @default.
- W4207064293 cites W3087409249 @default.
- W4207064293 cites W3092186007 @default.
- W4207064293 cites W3103071096 @default.
- W4207064293 cites W3111418631 @default.
- W4207064293 cites W3120592918 @default.
- W4207064293 cites W3158449324 @default.
- W4207064293 cites W3161431160 @default.
- W4207064293 cites W3197375825 @default.
- W4207064293 cites W3198760282 @default.
- W4207064293 cites W4231652916 @default.
- W4207064293 doi "https://doi.org/10.1002/cssc.202102532" @default.
- W4207064293 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34997695" @default.
- W4207064293 hasPublicationYear "2022" @default.
- W4207064293 type Work @default.
- W4207064293 citedByCount "7" @default.
- W4207064293 countsByYear W42070642932022 @default.
- W4207064293 countsByYear W42070642932023 @default.
- W4207064293 crossrefType "journal-article" @default.
- W4207064293 hasAuthorship W4207064293A5039783155 @default.
- W4207064293 hasAuthorship W4207064293A5042241049 @default.
- W4207064293 hasAuthorship W4207064293A5045152496 @default.
- W4207064293 hasAuthorship W4207064293A5048067331 @default.
- W4207064293 hasAuthorship W4207064293A5054030311 @default.
- W4207064293 hasAuthorship W4207064293A5080694348 @default.
- W4207064293 hasAuthorship W4207064293A5088019501 @default.
- W4207064293 hasConcept C161790260 @default.
- W4207064293 hasConcept C178790620 @default.
- W4207064293 hasConcept C181886296 @default.
- W4207064293 hasConcept C185592680 @default.
- W4207064293 hasConcept C2778659115 @default.