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- W4207079213 abstract "${mathrm{V}}_{2}{mathrm{O}}_{3}$ is an archetypical Mott material which exhibits Cr doping and/or temperature-induced paramagnetic metal to paramagnetic insulator/antiferromagnetic insulator (PM-PI/AFI) transitions. However, the strain effects on the metal-insulator transition (MIT) in thin films and the mechanisms behind them are not yet fully understood. In this study, we investigate the strain effects on the MIT in $({mathrm{V}}_{0.99}{mathrm{Cr}}_{0.01}{)}_{2}{mathrm{O}}_{3}$ (VC1) thin films growing on $c$-plane (001), $r$-plane (012), and $a$-plane (110) ${mathrm{Al}}_{2}{mathrm{O}}_{3}$ substrates. The strains can be tuned in a wide range over 1% in $mathrm{VC}1text{/}{mathrm{Al}}_{2}{mathrm{O}}_{3}$ thin films by changing the substrate temperature. Remarkably, the influence of strain on the MIT differs dramatically from (001)-oriented and non-(001)-oriented $mathrm{VC}1text{/}{mathrm{Al}}_{2}{mathrm{O}}_{3}$ thin films. The PM-PI transition can be effectively modulated by strain tuning in the (001) $mathrm{VC}1text{/}{mathrm{Al}}_{2}{mathrm{O}}_{3}$ thin films accompanied by gradual transformation from the PM/PI phase into the AFI phase upon cooling. On the contrary, both (012) and (110) $mathrm{VC}1text{/}{mathrm{Al}}_{2}{mathrm{O}}_{3}$ thin films exhibit sharp PM-AFI transitions irrespective of the strain states. The orientation-dependent strain effects on the MIT in the $mathrm{VC}1text{/}{mathrm{Al}}_{2}{mathrm{O}}_{3}$ thin films could be explained by the trigonal distortion within electronic correlation scenario. The trigonal distortion of $mathrm{V}(mathrm{Cr}){mathrm{O}}_{6}$ octahedra along (within) the $c$ axis ($ab$ plane) in the (001) $mathrm{VC}1text{/}{mathrm{Al}}_{2}{mathrm{O}}_{3}$ thin films can be directly modulated by the strains. However, the trigonal distortion in the (012) and (110) $mathrm{VC}1text{/}{mathrm{Al}}_{2}{mathrm{O}}_{3}$ thin films would hardly be affected due to the deviation of the film orientation from the $c$ axis. This explanation is experimentally confirmed by Raman spectra as a sensitive probe of the trigonal distortion in VC1 thin films. These results highlight the importance of trigonal distortion to understand the MIT in the ${mathrm{V}}_{2}{mathrm{O}}_{3}$ compound." @default.
- W4207079213 created "2022-01-26" @default.
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- W4207079213 date "2022-01-25" @default.
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- W4207079213 title "Orientation-dependent strain effects on the metal-insulator transitions in <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant=normal>V</mml:mi><mml:mrow><mml:mn>0.99</mml:mn></mml:mrow></mml:msub><mml:mrow><mml:msub><mml:mi mathvariant=normal>Cr</mml:mi><mml:mrow><mml:mn>0.01</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:mn>2</mml:mn></mml:msub></mml:mrow><mml:msub><mml:mi mathvariant=normal>O</mml…" @default.
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- W4207079213 doi "https://doi.org/10.1103/physrevb.105.035140" @default.
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