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- W4210277935 abstract "The reaction of silicon atoms with benzene molecules in solid neon is studied using matrix isolation infrared spectroscopy. Aided by carbon-13 and deuterium isotopic shifts as well as quantum-chemical calculations, the reaction intermediates and products are safely assigned. Among them, silicon atom addition to the aromatic π-system of benzene occurs in a [1,4] fashion Si[η2(1,4)-C6H6] complex (A) has been formed spontaneously on annealing, which further isomerizes to the seven-membered ring 1-silacycloheptatrienylidene (B) under UV light irradiation. A previously unconsidered five-membered ring 1-ethynyl-1H-silole (C) is generated as the final product under broadband UV light irradiation. The underlying reaction mechanism of complex A photo-isomerizing to species B and C is discussed in detail, which shows a remarkable boron-silicon diagonal relationship as compared to the reaction of boron with benzene in forming borole derivatives. The results presented herein provide new insight into the future design and synthesis of corresponding silole derivatives." @default.
- W4210277935 created "2022-02-08" @default.
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- W4210277935 date "2022-01-01" @default.
- W4210277935 modified "2023-10-14" @default.
- W4210277935 title "Matrix Infrared Spectra of 1-Ethynyl-1H-Silole Species from Reaction of Silicon Atoms with Benzene" @default.
- W4210277935 doi "https://doi.org/10.1039/d1cp05245d" @default.
- W4210277935 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35142314" @default.
- W4210277935 hasPublicationYear "2022" @default.
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