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• W4210278274 abstract "Abstract Supramolecular chemistry in confined spaces constructed from macrocyclic molecules has attracted much attention because it can utilize the specific binding properties of macrocyclic cavities. Herein we report the preparation of length‐controlled discrete tubular structures by homo‐/co‐assembly of rim‐differentiated and peralkylamino‐substituted pillar[5]arenes via hydrogen bonds and salt bridges. By dimerization and trimerization, the expanded tubes show a fivefold helical structure and stepwise binding, respectively. We found that the exchange speed of guest molecules in the tubes could be controlled by varying the tube length." @default.
• W4210278274 created "2022-02-08" @default.
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• W4210278274 date "2020-04-14" @default.
• W4210278274 modified "2023-10-09" @default.
• W4210278274 title "Non‐Covalent Interactions Enable the Length‐Controlled Generation of Discrete Tubes Capable of Guest Exchange" @default.
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• W4210278274 doi "https://doi.org/10.1002/ange.201916515" @default.
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