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- W4210306237 endingPage "1925" @default.
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- W4210306237 abstract "An asymmetric Friedel-Crafts C2-alkylation between 3-substituted indoles and imines catalyzed by chiral BINOL-derived disulfonimides (DSIs) has been developed. This reaction tolerated a wide range of 3-substituted indoles and imines, affording a series of chiral 2-indolyl methanamine derivatives in good yields with good to excellent enantioselectivities (up to 98% ee). This is a useful protocol for the direct synthesis of 2-indolyl methanamine derivatives. It is worth noting that increasing the temperature in this reaction could result in a better enantioselectivity, making it different from the other common organocatalytic systems." @default.
- W4210306237 created "2022-02-08" @default.
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- W4210306237 date "2022-01-01" @default.
- W4210306237 modified "2023-10-17" @default.
- W4210306237 title "Enantioselective synthesis of 2-indolyl methanamine derivatives through disulfonimide-catalyzed Friedel–Crafts C2-alkylation of 3-substituted indoles with imines" @default.
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- W4210306237 doi "https://doi.org/10.1039/d1ob02281d" @default.
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