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- W4210310538 abstract "A variety of functionalized sulfonium ylides were prepared in good yields through MnSO4-promoted S-O bond cleavage from activated alkynes and sulfoxides. Experimental results showed that the MnSO4 catalyst played important roles in accelerating the reaction and promoting the [1,3]-rearrangement of the S-O bond. Furthermore, the product was easily obtained on a gram scale by simple recrystallization without column chromatography. The obtained product can be converted to new sulfonium ylides and undergo cycloaddition with an alkyne to afford a trisubstituted furan scaffold." @default.
- W4210310538 created "2022-02-08" @default.
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- W4210310538 date "2022-01-01" @default.
- W4210310538 modified "2023-10-12" @default.
- W4210310538 title "MnSO<sub>4</sub>-promoted S–O bond cleavage for synthesizing functionalized sulfonium ylides from activated alkynes and sulfoxides" @default.
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- W4210310538 doi "https://doi.org/10.1039/d1ob02491d" @default.
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