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• W4210311170 endingPage "125820" @default.
• W4210311170 startingPage "125820" @default.
• W4210311170 abstract "Bromine is essential to scientific study and industrial application. However, the high toxicity, volatility and corrosivity of Br2 increase the risk of leakage or explosion. Using solid materials to capture bromine gas can alleviate the leakage and explosion. Herein, XBr3 (X = Cs, C8H20N and C16H36N) polybromide compounds, were synthesized by the one-pot Br2-free solvothermal method. CsBr3 can reversibly decompose and generate along with the release and capture of Br2 gas, while Br2 can be separated from aqueous solution in the form of Et4NBr3 (Et = Ethyl) or Bu4NBr3 (Bu = Butyl). CsBr3 can release 42.89% Br2 per molecular formula, which is the highest in reported crystalline materials so far. Bu4NBr can enrich Br2 in water with approximately 73% yield through the hydrophilic-hydrophobic effect. Our study presents an alternative method for solidification and efficient recycle of Br2." @default.
• W4210311170 created "2022-02-08" @default.
• W4210311170 creator A5048371400 @default.
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• W4210311170 date "2022-03-01" @default.
• W4210311170 modified "2023-09-27" @default.
• W4210311170 title "Br2-free method for XBr3 (X = Cs, C8H20N, C16H36N) synthesis: Br2 solid storage and separation from aqueous solution" @default.
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• W4210311170 doi "https://doi.org/10.1016/j.matchemphys.2022.125820" @default.
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