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- W4210342850 endingPage "14962" @default.
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- W4210342850 abstract "Molecular reactivity can change dramatically with the absorption of a photon due to the difference of the electronic configurations between the excited and ground states. Here we report on the discovery of a modular system (Schiff base formed from an aldehyde and an amine) that upon photoexcitation yields a more basic imine capable of intermolecular proton transfer from protic solvents. Ultrafast dynamics of the excited state conjugated Schiff base reveals the pathway for proton transfer, culminating in a 14-unit increase in pKa to give the excited state pKa*>20 in ethanol." @default.
- W4210342850 created "2022-02-08" @default.
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- W4210342850 date "2018-10-12" @default.
- W4210342850 modified "2023-09-27" @default.
- W4210342850 title "Ultrafast Dynamics of a “Super” Photobase" @default.
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- W4210342850 doi "https://doi.org/10.1002/ange.201806787" @default.
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