Matches in SemOpenAlex for { <https://semopenalex.org/work/W4210361163> ?p ?o ?g. }
- W4210361163 endingPage "3873" @default.
- W4210361163 startingPage "3862" @default.
- W4210361163 abstract "Abstract In this study, we report high‐entropy carbides synthesis with reactive bipolar high‐power impulse magnetron sputtering (HiPIMS). Uncontrolled microstructure and stoichiometry development with reactive gas flow rate are major limitations of conventional direct current (DC) and radio frequency (RF) magnetron sputtering of multicomponent carbides. With HiPIMS these chemically disordered crystals structurally and compositionally transform from a carbon‐deficient metallic (C/M < 1), to a stoichiometric ceramic zone (C/M ∼ 1), and to a nanocomposite embodiment (C/M > 1), as a function of the carbon content during HiPIMS deposition. X‐ray diffraction, X‐ray photoelectron spectroscopy, Raman spectroscopy, scanning electron microscopy, and nanoindentation hardness measurements are combined to demonstrate the three regions of synthesis domain. HiPIMS provides access to metallic, ceramic, and composite carbides with great control over the microstructure and stoichiometry, which is elusive in case of conventional DC and RF magnetron sputtering. Notably, the stoichiometric ceramic zone maintains a constant carbon to metal ratio (C/M ∼ 1) over an extended amount of methane flow before transitioning to a nanocomposite microstructure (C/M > 1). The transition zone breadth depends on materials affinity for carbon that correlates with valence electron concentration (VEC). As such, synthesis conditions for new high‐entropy carbides can be understood and predicted based on VEC." @default.
- W4210361163 created "2022-02-08" @default.
- W4210361163 creator A5005850270 @default.
- W4210361163 creator A5026283985 @default.
- W4210361163 creator A5039321634 @default.
- W4210361163 creator A5053018742 @default.
- W4210361163 date "2022-02-14" @default.
- W4210361163 modified "2023-10-16" @default.
- W4210361163 title "Bipolar high‐power impulse magnetron sputtering synthesis of high‐entropy carbides" @default.
- W4210361163 cites W1613484687 @default.
- W4210361163 cites W170895204 @default.
- W4210361163 cites W1778591116 @default.
- W4210361163 cites W1964859510 @default.
- W4210361163 cites W1968032279 @default.
- W4210361163 cites W1968848848 @default.
- W4210361163 cites W1971319331 @default.
- W4210361163 cites W1974757371 @default.
- W4210361163 cites W1975077281 @default.
- W4210361163 cites W1983885935 @default.
- W4210361163 cites W1984376041 @default.
- W4210361163 cites W1995933816 @default.
- W4210361163 cites W2004170261 @default.
- W4210361163 cites W2004982340 @default.
- W4210361163 cites W2009859313 @default.
- W4210361163 cites W2018672634 @default.
- W4210361163 cites W2022052913 @default.
- W4210361163 cites W2025113485 @default.
- W4210361163 cites W2031143421 @default.
- W4210361163 cites W2034066478 @default.
- W4210361163 cites W2053902070 @default.
- W4210361163 cites W2060244343 @default.
- W4210361163 cites W2061514612 @default.
- W4210361163 cites W2070008970 @default.
- W4210361163 cites W2070655161 @default.
- W4210361163 cites W2078924862 @default.
- W4210361163 cites W2082727122 @default.
- W4210361163 cites W2083004845 @default.
- W4210361163 cites W2084612219 @default.
- W4210361163 cites W2086933933 @default.
- W4210361163 cites W2119368217 @default.
- W4210361163 cites W2135814593 @default.
- W4210361163 cites W2150632585 @default.
- W4210361163 cites W2152466029 @default.
- W4210361163 cites W2235679284 @default.
- W4210361163 cites W2259577270 @default.
- W4210361163 cites W2543391933 @default.
- W4210361163 cites W2552215468 @default.
- W4210361163 cites W2556290125 @default.
- W4210361163 cites W2557627013 @default.
- W4210361163 cites W2560134656 @default.
- W4210361163 cites W2606778629 @default.
- W4210361163 cites W2767030598 @default.
- W4210361163 cites W2790089903 @default.
- W4210361163 cites W2790770045 @default.
- W4210361163 cites W2794777979 @default.
- W4210361163 cites W2795138227 @default.
- W4210361163 cites W2886553304 @default.
- W4210361163 cites W2899698325 @default.
- W4210361163 cites W2906646232 @default.
- W4210361163 cites W2907539358 @default.
- W4210361163 cites W2956000524 @default.
- W4210361163 cites W2967939435 @default.
- W4210361163 cites W3036384677 @default.
- W4210361163 cites W3043688647 @default.
- W4210361163 cites W3082925240 @default.
- W4210361163 cites W3171461314 @default.
- W4210361163 cites W351508309 @default.
- W4210361163 doi "https://doi.org/10.1111/jace.18392" @default.
- W4210361163 hasPublicationYear "2022" @default.
- W4210361163 type Work @default.
- W4210361163 citedByCount "1" @default.
- W4210361163 countsByYear W42103611632023 @default.
- W4210361163 crossrefType "journal-article" @default.
- W4210361163 hasAuthorship W4210361163A5005850270 @default.
- W4210361163 hasAuthorship W4210361163A5026283985 @default.
- W4210361163 hasAuthorship W4210361163A5039321634 @default.
- W4210361163 hasAuthorship W4210361163A5053018742 @default.
- W4210361163 hasConcept C113196181 @default.
- W4210361163 hasConcept C127413603 @default.
- W4210361163 hasConcept C134132462 @default.
- W4210361163 hasConcept C159985019 @default.
- W4210361163 hasConcept C171250308 @default.
- W4210361163 hasConcept C175708663 @default.
- W4210361163 hasConcept C185592680 @default.
- W4210361163 hasConcept C19067145 @default.
- W4210361163 hasConcept C191897082 @default.
- W4210361163 hasConcept C192562407 @default.
- W4210361163 hasConcept C22423302 @default.
- W4210361163 hasConcept C42360764 @default.
- W4210361163 hasConcept C43617362 @default.
- W4210361163 hasConcept C5335593 @default.
- W4210361163 hasConcept C61427134 @default.
- W4210361163 hasConcept C87976508 @default.
- W4210361163 hasConcept C92880739 @default.
- W4210361163 hasConcept C97892325 @default.
- W4210361163 hasConceptScore W4210361163C113196181 @default.
- W4210361163 hasConceptScore W4210361163C127413603 @default.
- W4210361163 hasConceptScore W4210361163C134132462 @default.