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• W4210366841 startingPage "232" @default.
• W4210366841 abstract "Single crystals of new rubidium sodium niobium fluoride, RbNaNbF7, were prepared by a hydrothermal reaction using HF solution. This fluoride crystallized in the orthorhombic space group Cmcm (#63) with a = 6.7031(6), b = 10.9813(11) and c = 8.2969(8) Å (Z = 4) and the final R factors (all reflections) are R = 0.0364 and wR2 = 0.0847. The crystal structure is formed by isolated polyhedra NbF7 with quasi pentagonal bi-pyramid geometry, and Na atom also forms NaF7 quasi pentagonal bi-pyramid polyhedron. Rb atom is coordinated by 8 fluorine atoms to form RbF8 tetragonal prism polyhedron. The position of one fluorine atom splits statistically, which coordinates Nb and Na ions. The tantalum analogue, RbNaTaF7 was the same crystal structure. This new rubidium sodium niobium fluoride exhibited photoluminescence properties by doping Mn4+ ion, which are similar to those of red phosphors. The emission intensity of RbNaNbF7:Mn4+ spectrum was inferior to those of KNaMF7:Mn4+ (M; Nb, Ta) on excitation at 455 nm." @default.
• W4210366841 created "2022-02-08" @default.
• W4210366841 creator A5040178914 @default.
• W4210366841 creator A5072598909 @default.
• W4210366841 date "2022-02-01" @default.
• W4210366841 modified "2023-09-25" @default.
• W4210366841 title "Hydrothermal synthesis and crystal structure of a new rubidium sodium niobium fluoride, RbNaNbF₇" @default.
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• W4210366841 doi "https://doi.org/10.2109/jcersj2.21147" @default.
• W4210366841 hasPublicationYear "2022" @default.
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