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- W4210367605 abstract "Developing efficient strategies for synthesizing novel diazocine compounds is valuable because their use has been limited by their synthetic accessibility. This work describes the catalytic (4+3) cycloaddition reaction of carbonyl ylides with azoalkenes generated in situ. The rhodium-catalyzed cascade reaction features good atom and step economy, providing the first access to oxo-bridged diazocines. The product could be synthesized on a gram scale and converted into diversely substituted dihydroisobenzofurans." @default.
- W4210367605 created "2022-02-08" @default.
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- W4210367605 date "2022-02-04" @default.
- W4210367605 modified "2023-10-15" @default.
- W4210367605 title "Construction of Oxo-Bridged Diazocines via Rhodium-Catalyzed (4+3) Cycloaddition of Carbonyl Ylides with Azoalkenes" @default.
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- W4210367605 doi "https://doi.org/10.1021/acs.orglett.2c00076" @default.
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