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- W4210370671 abstract "Adamantylideneadamantane 1,2-dioxetane (Adox), one of the most stable 1,2-dioxetanes, was used to investigate the kinetic properties of its chemiluminescent thermolytic reaction in the crystalline state by monitoring chemiluminescence (CL) in real time. Soon after heating of single crystals at 140 °C, it was found that the thermolytic reactions of Adox in the crystals proceeded with zero-order kinetics for several minutes. During the period showing the zero-order kinetics, CL intensities were dependent on the volumes of crystals, and the inside crystals were maintained in a thermal steady state with a constant thermal diffusivity. After this period, the heated crystals of Adox started to break showing different kinetics. This study indicates that a crystalline-state CL reaction is useful to track its progress in real time for analyzing the kinetics." @default.
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- W4210370671 date "2022-03-15" @default.
- W4210370671 modified "2023-09-29" @default.
- W4210370671 title "Intracrystalline Kinetics Analyzed by Real-Time Monitoring of a 1,2-Dioxetane Chemiluminescence Reaction in a Single Crystal" @default.
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- W4210370671 doi "https://doi.org/10.1246/bcsj.20210445" @default.
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