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• W4210386568 abstract "Compounds exhibiting main group elements in low oxidation states were found to mimic the reactivity of transition metal complexes. Like the latter, such main group species show a proclivity of changing their oxidation state as well as their coordination number by +2, therefore fulfilling the requirements for oxidative additions. Prominent examples of such main group compounds that undergo oxidative additions with organohalides R-X (R=alkyl, aryl, X=F, Cl, Br, I) are carbenes and their higher congeners. Aluminyl anions, which like carbenes and silylenes oxidatively add to strong σ-bonds in R-X species, have been recently discovered. We present the first anion based upon a Group 14 element, namely the tris(pentafluoroethyl)silanide anion, [Si(C2 F5 )3 ]- , which is capable of oxidative additions towards C-F bonds. This enables the isolation of non-chelated tetraorganofluorosilicate salts, which to the best of our knowledge had only been observed as reactive intermediates before." @default.
• W4210386568 created "2022-02-08" @default.
• W4210386568 creator A5009050687 @default.
• W4210386568 creator A5015231611 @default.
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• W4210386568 creator A5029807989 @default.
• W4210386568 creator A5065913948 @default.
• W4210386568 date "2022-02-28" @default.
• W4210386568 modified "2023-09-30" @default.
• W4210386568 title "Oxidative Additions of C−F Bonds to the Silanide Anion [Si(C ₂ F ₅ ) ₃ ] ⁻" @default.
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• W4210386568 doi "https://doi.org/10.1002/anie.202116468" @default.
• W4210386568 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35107847" @default.
• W4210386568 hasPublicationYear "2022" @default.
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