Matches in SemOpenAlex for { <https://semopenalex.org/work/W4210390744> ?p ?o ?g. }
- W4210390744 endingPage "3294" @default.
- W4210390744 startingPage "3280" @default.
- W4210390744 abstract "The post-synthetic exchange (PSE) method is a well-proven route to replace, modify, and add different functionalities to metal-organic frameworks (MOFs). Particularly, the solvent-assisted cation substitution (SACS) technique has been reported to prepare mixed-metal multivariate metal-organic frameworks (MTV-MOFs). However, such a technique does not apply to all types of MOFs. In 2013, Szilágyi et al. reported the achievement of the mixed-metal MTV-MIL-101 framework via PSE. Since then, a debate has been taking place about the validity of these findings. On the other hand, the attainment of the mixed-metal MIL-101 was reported to be obtainable through the direct synthesis, which is, to some, the only way to achieve it. Here, we settle this dispute by investigating Szilágyi's method not only as described, but also at extended conditions of time and different metal precursors: all attempts were vain. However, by reconsidering the refluxing solvent (dimethylformamide DMF instead of water) and the applied reaction conditions (110 °C-20 h), mixed-metal MIL-101(Cr/Fe) was achieved via a simple PSE method." @default.
- W4210390744 created "2022-02-08" @default.
- W4210390744 creator A5017523555 @default.
- W4210390744 creator A5051070244 @default.
- W4210390744 creator A5057028890 @default.
- W4210390744 creator A5088414412 @default.
- W4210390744 date "2022-01-01" @default.
- W4210390744 modified "2023-09-26" @default.
- W4210390744 title "Multivariate metal–organic framework MTV-MIL-101 <i>via</i> post-synthetic cation exchange: is it truly achievable?" @default.
- W4210390744 cites W1855030656 @default.
- W4210390744 cites W1972899713 @default.
- W4210390744 cites W1974335314 @default.
- W4210390744 cites W1977544708 @default.
- W4210390744 cites W1986150705 @default.
- W4210390744 cites W1986616529 @default.
- W4210390744 cites W1991124065 @default.
- W4210390744 cites W1992861508 @default.
- W4210390744 cites W1996352962 @default.
- W4210390744 cites W2007661885 @default.
- W4210390744 cites W2009368971 @default.
- W4210390744 cites W2015856769 @default.
- W4210390744 cites W2022357240 @default.
- W4210390744 cites W2025423215 @default.
- W4210390744 cites W2030489223 @default.
- W4210390744 cites W2033566441 @default.
- W4210390744 cites W2041777058 @default.
- W4210390744 cites W2053604634 @default.
- W4210390744 cites W2056775699 @default.
- W4210390744 cites W2072170322 @default.
- W4210390744 cites W2075137051 @default.
- W4210390744 cites W2075629163 @default.
- W4210390744 cites W2075805545 @default.
- W4210390744 cites W2081226089 @default.
- W4210390744 cites W2083966793 @default.
- W4210390744 cites W2084016038 @default.
- W4210390744 cites W2085349409 @default.
- W4210390744 cites W2085415828 @default.
- W4210390744 cites W2087754865 @default.
- W4210390744 cites W2093690161 @default.
- W4210390744 cites W2095189801 @default.
- W4210390744 cites W2099613551 @default.
- W4210390744 cites W2101632298 @default.
- W4210390744 cites W2106029391 @default.
- W4210390744 cites W2128962229 @default.
- W4210390744 cites W2136869681 @default.
- W4210390744 cites W2141939342 @default.
- W4210390744 cites W2161373841 @default.
- W4210390744 cites W2223615252 @default.
- W4210390744 cites W2230754323 @default.
- W4210390744 cites W227217638 @default.
- W4210390744 cites W2312340490 @default.
- W4210390744 cites W2316873365 @default.
- W4210390744 cites W2320627461 @default.
- W4210390744 cites W2325620268 @default.
- W4210390744 cites W2326211557 @default.
- W4210390744 cites W2327512659 @default.
- W4210390744 cites W2511475662 @default.
- W4210390744 cites W2523871742 @default.
- W4210390744 cites W2593558800 @default.
- W4210390744 cites W2616015649 @default.
- W4210390744 cites W2617846083 @default.
- W4210390744 cites W2750213389 @default.
- W4210390744 cites W2772667193 @default.
- W4210390744 cites W2900852739 @default.
- W4210390744 cites W2914268857 @default.
- W4210390744 cites W2936388882 @default.
- W4210390744 cites W2938467275 @default.
- W4210390744 cites W2946272478 @default.
- W4210390744 cites W2946965307 @default.
- W4210390744 cites W2962098455 @default.
- W4210390744 cites W2964344211 @default.
- W4210390744 cites W2967708589 @default.
- W4210390744 cites W3001305268 @default.
- W4210390744 cites W3012884023 @default.
- W4210390744 cites W3021794080 @default.
- W4210390744 cites W3044222457 @default.
- W4210390744 cites W3155116011 @default.
- W4210390744 cites W3203203294 @default.
- W4210390744 cites W4232624314 @default.
- W4210390744 cites W4242673452 @default.
- W4210390744 cites W4301078967 @default.
- W4210390744 cites W83493412 @default.
- W4210390744 doi "https://doi.org/10.1039/d1dt04222j" @default.
- W4210390744 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35133374" @default.
- W4210390744 hasPublicationYear "2022" @default.
- W4210390744 type Work @default.
- W4210390744 citedByCount "2" @default.
- W4210390744 countsByYear W42103907442022 @default.
- W4210390744 countsByYear W42103907442023 @default.
- W4210390744 crossrefType "journal-article" @default.
- W4210390744 hasAuthorship W4210390744A5017523555 @default.
- W4210390744 hasAuthorship W4210390744A5051070244 @default.
- W4210390744 hasAuthorship W4210390744A5057028890 @default.
- W4210390744 hasAuthorship W4210390744A5088414412 @default.
- W4210390744 hasConcept C119857082 @default.
- W4210390744 hasConcept C150394285 @default.
- W4210390744 hasConcept C161584116 @default.
- W4210390744 hasConcept C171250308 @default.