Matches in SemOpenAlex for { <https://semopenalex.org/work/W4210397827> ?p ?o ?g. }
- W4210397827 endingPage "2161" @default.
- W4210397827 startingPage "2153" @default.
- W4210397827 abstract "Chemical reduction of N,N'-bis(2-phosphonoethyl)-1,4,5,8-naphthalenediimide (PNDI) with the reducing agent sodium dithionite gave stable colored reduced species, both in homogeneous solutions and in self-assembled thin films. When colorless PNDI aqueous solutions were titrated with the reducing agent, stepwise reduction was observed, giving first the radical anion (PNDI-•) and then the dianion (PNDI2-) species, which were detected by UV-visible-NIR spectroscopy, allowing the unambiguous determination of absorption maxima and molar absorptivities for each species. The radical anion PNDI-• was found to form π-dimers in water, but monomeric PNDI-• was formed in the presence of the cationic surfactant cetyltrimethylammonium bromide, indicating association with the micelles. Thin films of PNDI with 25 layers were grown by the zirconium phosphonate method on quartz substrates. Reduction of the films with sodium dithionite also produced radical anions and dianions of PNDI. However, reduction in the films was much slower than in solution, evidencing the compactness of the films. Moreover, reduction in the films did not proceed to completion, even with excess of the reducing agent, which can be attributed to the repulsion of negative charges within the film." @default.
- W4210397827 created "2022-02-08" @default.
- W4210397827 creator A5021978933 @default.
- W4210397827 creator A5027268109 @default.
- W4210397827 creator A5057560071 @default.
- W4210397827 date "2022-02-01" @default.
- W4210397827 modified "2023-10-13" @default.
- W4210397827 title "Radical Anions and Dianions of Naphthalenediimides Generated within Layer-by-Layer Zirconium Phosphonate Thin Films" @default.
- W4210397827 cites W1975308483 @default.
- W4210397827 cites W1982662296 @default.
- W4210397827 cites W1982760389 @default.
- W4210397827 cites W1996790107 @default.
- W4210397827 cites W1999043089 @default.
- W4210397827 cites W2001069211 @default.
- W4210397827 cites W2015136545 @default.
- W4210397827 cites W2015625094 @default.
- W4210397827 cites W2031765885 @default.
- W4210397827 cites W2038015897 @default.
- W4210397827 cites W2038628207 @default.
- W4210397827 cites W2050923523 @default.
- W4210397827 cites W2072081089 @default.
- W4210397827 cites W2073757434 @default.
- W4210397827 cites W2074433812 @default.
- W4210397827 cites W2081728674 @default.
- W4210397827 cites W2089958958 @default.
- W4210397827 cites W2096345901 @default.
- W4210397827 cites W2216564307 @default.
- W4210397827 cites W2308715343 @default.
- W4210397827 cites W2326260942 @default.
- W4210397827 cites W2331239300 @default.
- W4210397827 cites W2335524479 @default.
- W4210397827 cites W2404045298 @default.
- W4210397827 cites W2516736712 @default.
- W4210397827 cites W2586486834 @default.
- W4210397827 cites W2730560300 @default.
- W4210397827 cites W2756158248 @default.
- W4210397827 cites W2766594744 @default.
- W4210397827 cites W2792853616 @default.
- W4210397827 cites W2793051734 @default.
- W4210397827 cites W2800902873 @default.
- W4210397827 cites W2804978939 @default.
- W4210397827 cites W2808651135 @default.
- W4210397827 cites W2884421899 @default.
- W4210397827 cites W2885229223 @default.
- W4210397827 cites W2901549506 @default.
- W4210397827 cites W2946536505 @default.
- W4210397827 cites W2949187170 @default.
- W4210397827 cites W2951384269 @default.
- W4210397827 cites W2997442276 @default.
- W4210397827 cites W3008436026 @default.
- W4210397827 cites W3022179860 @default.
- W4210397827 cites W3099971016 @default.
- W4210397827 cites W3128728899 @default.
- W4210397827 cites W3133724204 @default.
- W4210397827 cites W3183720835 @default.
- W4210397827 cites W3216213819 @default.
- W4210397827 cites W4254187222 @default.
- W4210397827 doi "https://doi.org/10.1021/acs.langmuir.1c03337" @default.
- W4210397827 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35104410" @default.
- W4210397827 hasPublicationYear "2022" @default.
- W4210397827 type Work @default.
- W4210397827 citedByCount "0" @default.
- W4210397827 crossrefType "journal-article" @default.
- W4210397827 hasAuthorship W4210397827A5021978933 @default.
- W4210397827 hasAuthorship W4210397827A5027268109 @default.
- W4210397827 hasAuthorship W4210397827A5057560071 @default.
- W4210397827 hasConcept C171250308 @default.
- W4210397827 hasConcept C178790620 @default.
- W4210397827 hasConcept C179104552 @default.
- W4210397827 hasConcept C181199279 @default.
- W4210397827 hasConcept C183882617 @default.
- W4210397827 hasConcept C184651966 @default.
- W4210397827 hasConcept C185592680 @default.
- W4210397827 hasConcept C186423591 @default.
- W4210397827 hasConcept C188027245 @default.
- W4210397827 hasConcept C19067145 @default.
- W4210397827 hasConcept C192562407 @default.
- W4210397827 hasConcept C2776300020 @default.
- W4210397827 hasConcept C2777315085 @default.
- W4210397827 hasConcept C2777626080 @default.
- W4210397827 hasConcept C2779500173 @default.
- W4210397827 hasConcept C534791751 @default.
- W4210397827 hasConcept C75473681 @default.
- W4210397827 hasConceptScore W4210397827C171250308 @default.
- W4210397827 hasConceptScore W4210397827C178790620 @default.
- W4210397827 hasConceptScore W4210397827C179104552 @default.
- W4210397827 hasConceptScore W4210397827C181199279 @default.
- W4210397827 hasConceptScore W4210397827C183882617 @default.
- W4210397827 hasConceptScore W4210397827C184651966 @default.
- W4210397827 hasConceptScore W4210397827C185592680 @default.
- W4210397827 hasConceptScore W4210397827C186423591 @default.
- W4210397827 hasConceptScore W4210397827C188027245 @default.
- W4210397827 hasConceptScore W4210397827C19067145 @default.
- W4210397827 hasConceptScore W4210397827C192562407 @default.
- W4210397827 hasConceptScore W4210397827C2776300020 @default.
- W4210397827 hasConceptScore W4210397827C2777315085 @default.
- W4210397827 hasConceptScore W4210397827C2777626080 @default.
- W4210397827 hasConceptScore W4210397827C2779500173 @default.