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- W4210403669 abstract "The effects of β-hydrogen-containing alkyl Grignard reagents in simple ferric salt cross-couplings have been elucidated. The reaction of FeCl3 with EtMgBr in THF leads to the formation of the cluster species [Fe8Et12]2−, a rare example of a structurally characterized metal complex with bridging ethyl ligands. Analogous reactions in the presence of NMP, a key additive for effective cross-coupling with simple ferric salts and β-hydrogen-containing alkyl nucleophiles, result in the formation of [FeEt3]−. Reactivity studies demonstrate the effectiveness of [FeEt3]− in rapidly and selectively forming the cross-coupled product upon reaction with electrophiles. The identification of iron-ate species with EtMgBr analogous to those previously observed with MeMgBr is a critical insight, indicating that analogous iron species can be operative in catalysis for these two classes of alkyl nucleophiles." @default.
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- W4210403669 date "2019-01-29" @default.
- W4210403669 modified "2023-10-10" @default.
- W4210403669 title "The Effect of β‐Hydrogen Atoms on Iron Speciation in Cross‐Couplings with Simple Iron Salts and Alkyl Grignard Reagents" @default.
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- W4210403669 doi "https://doi.org/10.1002/ange.201813578" @default.
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