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- W4210433612 abstract "• Higher doping concentration is found to be ion-trapping agent, have high N-I temperature and dielectric permittivity. • Activation energy has been decreased with the dispersion of Co NPs. • Presence of Co NPs reduces the threshold voltage. • Nearly 15% and 5% increment in birefringence and order parameter was observed at low amount of NPs. • Manifestation of strong coupling between LC director and dipole moment of Co MNPs was noticed. In the present study, different concentrations of carbon coated cobalt nanoparticles (0.25 wt% & 0.5 wt%) into eutectic nematic liquid crystal mixture (E7) have been dispersed and studied their mesomorphic, electro-optic and dielectric properties in planar as well as homeotropic aligned cells. Optical transmission method has been employed in planar aligned cell to study the electro-optic responses while dielectric spectroscopy in the frequency span 20 Hz-10 MHz has been performed in planar and homeotropic cells. Nearly 10°C increase in nematic-isotropic transition temperature is noticed at higher doping concentration. Dispersion of cobalt nanoparticles induces changes in dielectric permittivity, dielectric loss and relaxation frequency. Suppression of free ion concentration (in case of 0.5 wt% Co) suggests large dielectric anisotropy values. Entropy of the system is more or less affected with the nano inclusions but the free energy of the doped samples has been decreased. An improvement in threshold voltage, birefringence and order parameter by ∼ 10%, 15% & 5% respectively have been observed at low doping concentration. However, contrast ratio is reduced with the doping of cobalt nanoparticles. The present study shows that the doped systems have improved response than pure E7 and find potential applications in phase shifters as well as display devices." @default.
- W4210433612 created "2022-02-08" @default.
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- W4210433612 date "2022-04-01" @default.
- W4210433612 modified "2023-10-02" @default.
- W4210433612 title "Mesomorphic, electro-optic and dielectric behavior of self-assembled nanocomposite materials: Nematic mixture doped with carbon coated cobalt nanoparticles" @default.
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- W4210433612 doi "https://doi.org/10.1016/j.molliq.2022.118639" @default.
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