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- W4210442015 abstract "The first chemical synthesis of tetravinylallene (3,5-divinylhepta-1,3,4,6-tetraene) is reported. The final, key step of the synthesis involves a palladium-catalyzed, Negishi-type cross-coupling involving 1,5-transposition of a penta-2-en-4-yn-1-ol methanesulfonate. The unprecedented fundamental hydrocarbon is sufficiently stable to be purified by flash chromatography. A similar synthetic pathway grants access to the first substituted tetravinylallenes, which provide insights into the influence of substitution upon stability and reactivity. Tetravinylallenes are shown to break new ground in swift structural complexity creation, with three novel sequences reported." @default.
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- W4210442015 date "2019-08-30" @default.
- W4210442015 modified "2023-10-18" @default.
- W4210442015 title "Tetravinylallene" @default.
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- W4210442015 doi "https://doi.org/10.1002/anie.201908496" @default.
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