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- W4210465943 endingPage "15103" @default.
- W4210465943 startingPage "15099" @default.
- W4210465943 abstract "Abstract The regioselective conversion of C−H bonds into C−Si bonds is extremely important owing to the natural abundance and non‐toxicity of silicon. Classical silylation reactions often suffer from poor functional group compatibility, low atom economy, and insufficient regioselectivity. Herein, we disclose a template‐assisted method for the regioselective para silylation of toluene derivatives. A new template was designed, and the origin of selectivity was analyzed experimentally and computationally. An interesting substrate–solvent hydrogen‐bonding interaction was observed. Kinetic, spectroscopic, and computational studies shed light on the reaction mechanism. The synthetic significance of this strategy was highlighted by the generation of a precursor of a potential lipophilic bioisostere of γ‐aminobutyric acid (GABA), various late‐stage diversifications, and by mimicking enzymatic transformations." @default.
- W4210465943 created "2022-02-08" @default.
- W4210465943 creator A5016811639 @default.
- W4210465943 creator A5021833788 @default.
- W4210465943 creator A5027298870 @default.
- W4210465943 creator A5051885484 @default.
- W4210465943 creator A5062100333 @default.
- W4210465943 creator A5070221610 @default.
- W4210465943 creator A5074582456 @default.
- W4210465943 date "2017-10-25" @default.
- W4210465943 modified "2023-09-25" @default.
- W4210465943 title "Experimental and Computational Exploration of <i>para</i> ‐Selective Silylation with a Hydrogen‐Bonded Template" @default.
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- W4210465943 doi "https://doi.org/10.1002/ange.201708449" @default.