Matches in SemOpenAlex for { <https://semopenalex.org/work/W4210492718> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W4210492718 endingPage "12369" @default.
- W4210492718 startingPage "12365" @default.
- W4210492718 abstract "Abstract The reaction of nitroxyl radicals TEMPO (2,2′,6,6′‐tetramethylpiperidinyloxyl) and AZADO (2‐azaadamantane‐N‐oxyl) with an iron(I) synthon affords iron(II)‐nitroxido complexes ( Ar L)Fe(κ 1 ‐TEMPO) and ( Ar L)Fe(κ 2 ‐N,O‐AZADO) ( Ar L=1,9‐(2,4,6‐Ph 3 C 6 H 2 ) 2 ‐5‐mesityldipyrromethene). Both high‐spin iron(II)‐nitroxido species are stable in the absence of weak C−H bonds, but decay via N−O bond homolysis to ferrous or ferric iron hydroxides in the presence of 1,4‐cyclohexadiene. Whereas ( Ar L)Fe(κ 1 ‐TEMPO) reacts to give a diferrous hydroxide [( Ar L)Fe] 2 (μ‐OH) 2 , the reaction of four‐coordinate ( Ar L)Fe(κ 2 ‐N,O‐AZADO) with hydrogen atom donors yields ferric hydroxide ( Ar L)Fe(OH)(AZAD). Mechanistic experiments reveal saturation behavior in C−H substrate and are consistent with rate‐determining hydrogen atom transfer." @default.
- W4210492718 created "2022-02-08" @default.
- W4210492718 creator A5007109794 @default.
- W4210492718 creator A5008401373 @default.
- W4210492718 creator A5022569799 @default.
- W4210492718 creator A5036001834 @default.
- W4210492718 date "2017-08-25" @default.
- W4210492718 modified "2023-09-25" @default.
- W4210492718 title "C−H Activation from Iron(II)‐Nitroxido Complexes" @default.
- W4210492718 cites W1767167377 @default.
- W4210492718 cites W1967700647 @default.
- W4210492718 cites W1967971835 @default.
- W4210492718 cites W1969578816 @default.
- W4210492718 cites W1999125811 @default.
- W4210492718 cites W2006112803 @default.
- W4210492718 cites W2011278625 @default.
- W4210492718 cites W2013034718 @default.
- W4210492718 cites W2021426561 @default.
- W4210492718 cites W2022987827 @default.
- W4210492718 cites W2023397806 @default.
- W4210492718 cites W2034796508 @default.
- W4210492718 cites W2039397684 @default.
- W4210492718 cites W2052709412 @default.
- W4210492718 cites W2061017523 @default.
- W4210492718 cites W2061680177 @default.
- W4210492718 cites W2062526814 @default.
- W4210492718 cites W2067718414 @default.
- W4210492718 cites W2077098054 @default.
- W4210492718 cites W2078887629 @default.
- W4210492718 cites W2080333152 @default.
- W4210492718 cites W2083280040 @default.
- W4210492718 cites W2083644366 @default.
- W4210492718 cites W2086844296 @default.
- W4210492718 cites W2106487454 @default.
- W4210492718 cites W2131027449 @default.
- W4210492718 cites W2226953743 @default.
- W4210492718 cites W2290916158 @default.
- W4210492718 cites W2315719161 @default.
- W4210492718 cites W2326727947 @default.
- W4210492718 cites W2338151994 @default.
- W4210492718 cites W2396149065 @default.
- W4210492718 cites W2609467608 @default.
- W4210492718 cites W2949382717 @default.
- W4210492718 cites W4236683059 @default.
- W4210492718 doi "https://doi.org/10.1002/ange.201706594" @default.
- W4210492718 hasPublicationYear "2017" @default.
- W4210492718 type Work @default.
- W4210492718 citedByCount "3" @default.
- W4210492718 countsByYear W42104927182018 @default.
- W4210492718 countsByYear W42104927182021 @default.
- W4210492718 countsByYear W42104927182022 @default.
- W4210492718 crossrefType "journal-article" @default.
- W4210492718 hasAuthorship W4210492718A5007109794 @default.
- W4210492718 hasAuthorship W4210492718A5008401373 @default.
- W4210492718 hasAuthorship W4210492718A5022569799 @default.
- W4210492718 hasAuthorship W4210492718A5036001834 @default.
- W4210492718 hasBestOaLocation W42104927181 @default.
- W4210492718 hasConcept C139066938 @default.
- W4210492718 hasConcept C155647269 @default.
- W4210492718 hasConcept C178790620 @default.
- W4210492718 hasConcept C179104552 @default.
- W4210492718 hasConcept C185592680 @default.
- W4210492718 hasConcept C2775832776 @default.
- W4210492718 hasConcept C2775896084 @default.
- W4210492718 hasConcept C2780534640 @default.
- W4210492718 hasConcept C40869318 @default.
- W4210492718 hasConcept C71240020 @default.
- W4210492718 hasConceptScore W4210492718C139066938 @default.
- W4210492718 hasConceptScore W4210492718C155647269 @default.
- W4210492718 hasConceptScore W4210492718C178790620 @default.
- W4210492718 hasConceptScore W4210492718C179104552 @default.
- W4210492718 hasConceptScore W4210492718C185592680 @default.
- W4210492718 hasConceptScore W4210492718C2775832776 @default.
- W4210492718 hasConceptScore W4210492718C2775896084 @default.
- W4210492718 hasConceptScore W4210492718C2780534640 @default.
- W4210492718 hasConceptScore W4210492718C40869318 @default.
- W4210492718 hasConceptScore W4210492718C71240020 @default.
- W4210492718 hasFunder F4320306076 @default.
- W4210492718 hasFunder F4320306080 @default.
- W4210492718 hasIssue "40" @default.
- W4210492718 hasLocation W42104927181 @default.
- W4210492718 hasLocation W42104927182 @default.
- W4210492718 hasOpenAccess W4210492718 @default.
- W4210492718 hasPrimaryLocation W42104927181 @default.
- W4210492718 hasRelatedWork W1976110508 @default.
- W4210492718 hasRelatedWork W2006382785 @default.
- W4210492718 hasRelatedWork W2014819731 @default.
- W4210492718 hasRelatedWork W2017806787 @default.
- W4210492718 hasRelatedWork W2058862899 @default.
- W4210492718 hasRelatedWork W2065873897 @default.
- W4210492718 hasRelatedWork W2080051594 @default.
- W4210492718 hasRelatedWork W2406552795 @default.
- W4210492718 hasRelatedWork W4247256858 @default.
- W4210492718 hasRelatedWork W72124097 @default.
- W4210492718 hasVolume "129" @default.
- W4210492718 isParatext "false" @default.
- W4210492718 isRetracted "false" @default.
- W4210492718 workType "article" @default.