Matches in SemOpenAlex for { <https://semopenalex.org/work/W4210620390> ?p ?o ?g. }
- W4210620390 abstract "The development of a facile strategy to construct defect-free and flexible metal-organic framework (MOF)-based membranes with high selectivity and good scalability holds great appeal. Here we report the fabrication of soft-solid MOF composite membranes on polyvinylidene fluoride substrates. A representative membrane comprised of quasi-vertically grown lamellar Zn2 (Bim)4 (Bim=benzimidazolate) and lateral ultrathin polyamide film adhering to the MOF side facets. The straight interlayer galleries within unwrapped Zn2 (Bim)4 acted as predominant pathways, while the polyamide served the function of defect elimination, synergistically inducing an unprecedented H2 /CO2 selectivity of 1084 which set a new record for MOF-based membranes. Separation performance was held constant after membrane rolling up into a tube with a diameter of 3 mm or folding and unfolding at 90° for 50 times. ZIF-67 and ZIF-8 composite membranes based on this strategy also realized extremely high H2 /CO2 separation accuracies. These results, which demonstrate the intrinsic molecular sieving capability of MOFs, will promote the development of MOF-based membranes in practical separation applications." @default.
- W4210620390 created "2022-02-08" @default.
- W4210620390 creator A5000264619 @default.
- W4210620390 creator A5001301417 @default.
- W4210620390 creator A5001796793 @default.
- W4210620390 creator A5025344536 @default.
- W4210620390 creator A5074053052 @default.
- W4210620390 creator A5088131408 @default.
- W4210620390 date "2022-02-16" @default.
- W4210620390 modified "2023-10-17" @default.
- W4210620390 title "Flexible Soft‐Solid Metal–Organic Framework Composite Membranes for H <sub>2</sub> /CO <sub>2</sub> Separation" @default.
- W4210620390 cites W1973260029 @default.
- W4210620390 cites W1991914667 @default.
- W4210620390 cites W1998279652 @default.
- W4210620390 cites W2020147547 @default.
- W4210620390 cites W2022353023 @default.
- W4210620390 cites W2040057498 @default.
- W4210620390 cites W2067558104 @default.
- W4210620390 cites W2080820570 @default.
- W4210620390 cites W2082614835 @default.
- W4210620390 cites W2108035243 @default.
- W4210620390 cites W2168570857 @default.
- W4210620390 cites W2316236480 @default.
- W4210620390 cites W2325310297 @default.
- W4210620390 cites W2596043326 @default.
- W4210620390 cites W2621508343 @default.
- W4210620390 cites W2625153997 @default.
- W4210620390 cites W2730533679 @default.
- W4210620390 cites W2749157016 @default.
- W4210620390 cites W2753454358 @default.
- W4210620390 cites W2764184599 @default.
- W4210620390 cites W2890080368 @default.
- W4210620390 cites W2894851953 @default.
- W4210620390 cites W2904058439 @default.
- W4210620390 cites W2904929342 @default.
- W4210620390 cites W2920845230 @default.
- W4210620390 cites W2922422619 @default.
- W4210620390 cites W2991651952 @default.
- W4210620390 cites W2997053276 @default.
- W4210620390 cites W3005583752 @default.
- W4210620390 cites W3033251340 @default.
- W4210620390 cites W3036596481 @default.
- W4210620390 cites W3039136197 @default.
- W4210620390 cites W3047684425 @default.
- W4210620390 cites W3047767152 @default.
- W4210620390 cites W3090760097 @default.
- W4210620390 cites W3093418049 @default.
- W4210620390 cites W3108668196 @default.
- W4210620390 cites W3109302533 @default.
- W4210620390 cites W3118277210 @default.
- W4210620390 cites W3120420175 @default.
- W4210620390 cites W3121452419 @default.
- W4210620390 cites W3185829662 @default.
- W4210620390 cites W4206192409 @default.
- W4210620390 cites W4206724620 @default.
- W4210620390 cites W4240813209 @default.
- W4210620390 cites W4242058987 @default.
- W4210620390 cites W4250796442 @default.
- W4210620390 doi "https://doi.org/10.1002/anie.202117577" @default.
- W4210620390 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35103369" @default.
- W4210620390 hasPublicationYear "2022" @default.
- W4210620390 type Work @default.
- W4210620390 citedByCount "27" @default.
- W4210620390 countsByYear W42106203902022 @default.
- W4210620390 countsByYear W42106203902023 @default.
- W4210620390 crossrefType "journal-article" @default.
- W4210620390 hasAuthorship W4210620390A5000264619 @default.
- W4210620390 hasAuthorship W4210620390A5001301417 @default.
- W4210620390 hasAuthorship W4210620390A5001796793 @default.
- W4210620390 hasAuthorship W4210620390A5025344536 @default.
- W4210620390 hasAuthorship W4210620390A5074053052 @default.
- W4210620390 hasAuthorship W4210620390A5088131408 @default.
- W4210620390 hasConcept C104779481 @default.
- W4210620390 hasConcept C118792377 @default.
- W4210620390 hasConcept C127413603 @default.
- W4210620390 hasConcept C130797344 @default.
- W4210620390 hasConcept C136525101 @default.
- W4210620390 hasConcept C142724271 @default.
- W4210620390 hasConcept C150394285 @default.
- W4210620390 hasConcept C159985019 @default.
- W4210620390 hasConcept C161790260 @default.
- W4210620390 hasConcept C171250308 @default.
- W4210620390 hasConcept C178790620 @default.
- W4210620390 hasConcept C179366358 @default.
- W4210620390 hasConcept C18411161 @default.
- W4210620390 hasConcept C185592680 @default.
- W4210620390 hasConcept C188027245 @default.
- W4210620390 hasConcept C190399342 @default.
- W4210620390 hasConcept C192562407 @default.
- W4210620390 hasConcept C204787440 @default.
- W4210620390 hasConcept C2776254723 @default.
- W4210620390 hasConcept C41625074 @default.
- W4210620390 hasConcept C42360764 @default.
- W4210620390 hasConcept C55493867 @default.
- W4210620390 hasConcept C71924100 @default.
- W4210620390 hasConcept C77851909 @default.
- W4210620390 hasConcept C85268084 @default.
- W4210620390 hasConceptScore W4210620390C104779481 @default.
- W4210620390 hasConceptScore W4210620390C118792377 @default.
- W4210620390 hasConceptScore W4210620390C127413603 @default.