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- W4210657807 abstract "[7772-99-8] Cl2Sn (MW 189.61) InChI = 1S/2ClH.Sn/h2*1H;/q;;+2/p-2 InChIKey = AXZWODMDQAVCJE-UHFFFAOYSA-L (reducing agent for many functional groups; carbonyl allylation; Lewis acid catalyst in C–C bond-forming reactions; catalyst with AgClO4 for the synthesis of α-glycosides; synthesis of alkenes, dienes, cis-vinyloxiranes, and allylic selenides; deoxygenation of 1,4-endoperoxides; protection of carboxylic acids as 1,3-dithianes; selective p-methoxybenzyl ether cleavage reagent; additive in hydroformylation and carbonylation reactions1) Alternate Name: stannous chloride. Physical Data: mp 246.8 °C; bp 623 °C; d 3.95 g cm−3. Solubility: insol xylenes; sol water, ethanol, acetone, diethyl ether, methyl acrylate, methyl ethyl ketone, isobutyl alcohol. Form Supplied in: white crystalline solid; widely available. Preparative Methods: analytical reagent grade tin(II) chloride is prepared by adding the dihydrate to a vigorously stirred solution of acetic anhydride (120 g salt per 100 g anhydride). After ca. one hour, the anhydrous SnCl2 is filtered on a dry sintered glass or Buchner funnel, washed free from acetic acid with dry Et2O, and dried in vacuo. It is best stored in a sealed container.2" @default.
- W4210657807 created "2022-02-08" @default.
- W4210657807 creator A5031747642 @default.
- W4210657807 creator A5077542724 @default.
- W4210657807 date "2005-10-15" @default.
- W4210657807 modified "2023-10-18" @default.
- W4210657807 title "Tin(II) Chloride" @default.
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- W4210657807 doi "https://doi.org/10.1002/047084289x.rt112" @default.
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