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- W4210766730 abstract "Abstract C-Alkyl glycosides represent an attractive class of nonhydrolyzable carbohydrate mimetics which possess enormous potential as next-generation therapeutics. Methods for the direct stereoselective synthesis of C-alkyl glycosides with a broad substrate tolerance are limited, however. This is especially in the case of β-linked C-alkyl glycosides, where direct methods for synthesis from commonly available coupling partners remain limited. This Account describes the evolution of our laboratory’s studies on glycosyl sulfonate chemistry from a method for the construction of simple β-linked 2-deoxy-sugars to a technology for the direct synthesis of β-linked acyl and homoacyl glycosides that can be elaborated into more complex structures. 1 Introduction 2 Glycosyl Sulfonates 3 Glycosyl Sulfonates in Oligosaccharide Synthesis 4 Matching Donor and Sulfonate Reactivity 5 β-Linked C-Acyl and Homoacyl Glycoside Synthesis 6 Elaboration to other Products 7 Conclusion" @default.
- W4210766730 created "2022-02-08" @default.
- W4210766730 creator A5009403356 @default.
- W4210766730 date "2022-01-31" @default.
- W4210766730 modified "2023-09-24" @default.
- W4210766730 title "Evolution of a Reagent-Controlled Strategy for β-Selective C-Glycoside Synthesis" @default.
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- W4210766730 doi "https://doi.org/10.1055/a-1755-3090" @default.
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