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- W4210782019 abstract "Abstract Cyclopropanone, the simplest member of the cyclic ketones, has fascinated organic chemists for decades. Although its (attempted) synthesis was reported as early as 18902, its first preparation dates back to 1932, when Lipp3 et al. succeeded in isolating 1,1-dihydroxycyclopropane from the reaction of diazomethane with an excess of ketene. Much later, in 1966, Schaafsma1 succeeded in isolating the free ketone prepared iron the same reagents by using liquid propane as the solvent. At about the same time, the (dissolved) ketone was also characterized by Turro and Hammond.5 Cyclopropanone undergoes a rapid reaction with all types of nucleophiles6,7, and many of the resulting 1-substituted" @default.
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- W4210782019 date "1973-01-01" @default.
- W4210782019 modified "2023-10-09" @default.
- W4210782019 title "The Chemistry of Small Ring Compounds. Part 23<sup>1</sup>Improved Synthesis of Cyclopropanone and Some 1-Substituted Cyclopropanols" @default.
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- W4210782019 doi "https://doi.org/10.1080/00397917308062034" @default.
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