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- W4210849401 abstract "The crystallization of CuInSe2 thin films by high Se vapour selenization of co-sputtered Cu-In alloy precursor within a partially closed graphite container is reported. X-ray diffusion (XRD) analysis of the Cu-In alloy films displayed mainly the CuIn2 and Cu11In9 phases. A three-fold volume expansion was recorded in all the selenized CuInSe2 films at 500–550°C. Large and densely packed crystals with sizes of about 5 μm were exhibited by the films irrespective of whether they were Cu-rich or In-rich. Single phase chalcopyrite CuInSe2 structure with preferential orientation in the (112) direction were obtained. Films with a wide range of compositions (Cu/In of 0.43–1.2 and Se/(Cu+In) of 0.92–1.47) were fabricated. All the films where Se rich, with the exception of samples with very high Cu content. The measured film resistivities varied from 10−1 to 105 Ω-cm in consistence with the increasing Cu content of the alloy precursor during deposition. The alloy films with very high In content yielded the CuIn2Se3.5 or CuIn3Se5 compound as determined from XRD and EDX analyses. A study of the reaction mechanism performed between 250 and 550°C indicated that the crystal growth was assisted by the formation of the CuSe flux agent. The development of a suitable window layer to test the photovoltaic properties of these films is currently in progress." @default.
- W4210849401 created "2022-02-09" @default.
- W4210849401 date "2000-11-01" @default.
- W4210849401 modified "2023-10-17" @default.
- W4210849401 title "00/03508 On the relationship between duration of sunshine and solar radiation on the earth's surface: Ångström's equation revisited" @default.
- W4210849401 doi "https://doi.org/10.1016/s0140-6701(00)94580-6" @default.
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