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• W4210971538 endingPage "1932" @default.
• W4210971538 startingPage "1926" @default.
• W4210971538 abstract "A method of direct borylation of vinyl-substituted porphyrinoids (porphyrins and chlorins) has been developed based on the copper catalyzed vinylic C-H activation. Ni(II) complexes of meso- and β-vinylporphyrinoids have been transformed to the corresponding pinacolboronated derivatives with good yields and high (E)-stereoselectivity. The method provides an easy and direct access to the valuable synthons which were shown to act as nucleophylic partners in the Suzuki cross-coupling building tetrapyrrole derivatives with π-conjugation through the carbon-carbon double bond." @default.
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• W4210971538 date "2022-01-01" @default.
• W4210971538 modified "2023-09-26" @default.
• W4210971538 title "Direct C–H borylation of vinylporphyrins <i>via</i> copper catalysis" @default.
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• W4210971538 doi "https://doi.org/10.1039/d1ob02005f" @default.
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