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- W4210996834 abstract "Abstract Herein, we report a Cu‐catalyzed enantioselective allylic alkylation using a γ‐butyrolactone‐derived silyl ketene acetal. Critical to the development of this work was the identification of a novel mono‐picolinamide ligand with the appropriate steric and electronic properties to afford the desired products in high yield (up to 96 %) and high ee (up to 95 %). Aryl, aliphatic, and unsubstituted allylic chlorides bearing a broad range of functionality are well‐tolerated. Spectroscopic studies reveal that a Cu I species is likely the active catalyst, and DFT calculations suggest ligand sterics play an important role in determining Cu coordination and thus catalyst geometry." @default.
- W4210996834 created "2022-02-13" @default.
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- W4210996834 date "2019-12-16" @default.
- W4210996834 modified "2023-09-26" @default.
- W4210996834 title "Copper‐Catalyzed Enantioselective Allylic Alkylation with a γ‐Butyrolactone‐Derived Silyl Ketene Acetal" @default.
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- W4210996834 doi "https://doi.org/10.1002/ange.201912618" @default.
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