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• W4211018120 endingPage "226" @default.
• W4211018120 startingPage "123" @default.
• W4211018120 abstract "This chapter contains sections titled: Oxidation by Metal Ions and Related Species Chromium, Manganese, Nickel, and Cobalt Copper, Silver, Gold, and Thallium Cerium, Tungsten, Molybdenum and Vanadium Palladium, Iridium, Ruthenium, and Platinum Group VIII Metals Oxidation by Compounds of Non-metallic Elements Nitrogen, Phosphorus, and Sulfur Halogens Ozonolysis and Ozonation Peracids and Peroxides Photo-oxygenation and Singlet Oxygen Triplet Oxygen and Autoxidation Other Oxidations Reduction by Complex Metal Hydrides Hydrogenation Transfer Hydrogenation Other Reductions References The oxidation of deuterated benzyl alcohol with imidazolium fluorochro-mate (IFC) exhibits a substantial primary kinetic isotope effect. The rates of oxidation of para– and meta-substituted benzyl alcohols correlate well in terms of Charton's triparametric localized, delocalized and resonance-demand (LDR) equation, whereas the oxidation of the ortho-substituted compounds correlate with the tetraparametric LDR steric (LDRS) equation with negative polar reaction constants. This chapter explores the kinetics of the oxidation of some ahydroxy acids by quinolinium chlorochromate (QCC). It analyses the kinetic and activation parameters of the oxidation of thiourea with quinolinium dichromate. Strained alkynes including arynes and cyclooctynes reacted with N–methoxyamides through palladium-catalysed CH/NH activation to yield important N–heterocycles such as phenanthridinones and isoquinolones in one step with high efficiency. The reduction of secondary allyl amides with lithium aluminium hydride (LAH) often leads to a concomitant reduction, producing n–propylamine derivatives. Borohydride reduction of salicylaldehyde imines yields a cyclic boramide." @default.
• W4211018120 created "2022-02-13" @default.
• W4211018120 creator A5024864485 @default.
• W4211018120 date "2017-12-22" @default.
• W4211018120 modified "2023-10-05" @default.
• W4211018120 title "Oxidation and Reduction" @default.
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