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- W4211022969 abstract "The van der Waals equation of state is used for correlation (using a single binary interaction parameter) and prediction of liquid-liquid equilibrium in many mixtures including a solvent and a polymer. The equation of state parameters for the polymer are estimated from experimental volumetric data at low pressures. For the solvent, the equation of state parameters are estimated via the classical method, i.e. using the critical properties of the solvent and generalized expressions of the acentric factor. When extended to mixtures, the van der Waals one-fluid mixing rules along with the Berthelot combining rule for the molecular cross energy parameter are used. The arithmetic mean combining rule is used for the cross co-volume parameter. A correction to the Berthelot combining rule which is obtained from vapor-liquid equilibrium data of polymer solutions is used for predicting the upper critical solution temperatures for many different binary polymer solutions, including polar and non-polar systems. The results are remarkably successful. Typically, the difference between the predicted and the experimental upper critical solution temperatures is less than twenty degrees. Further, in all cases, correlation is achieved in an easy and straightforward way without difficulty and excellent results are obtained. Unlike other theories and models, the van der Waals equation of state is capable of predicting the flatness of the coexistence curves, which often occurs in polymer solutions." @default.
- W4211022969 created "2022-02-13" @default.
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- W4211022969 creator A5030313091 @default.
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- W4211022969 date "1994-09-01" @default.
- W4211022969 modified "2023-10-05" @default.
- W4211022969 title "Application of the van der Waals equation of state to polymers III. Correlation and prediction of upper critical solution temperatures for polymer solutions" @default.
- W4211022969 cites W1537273942 @default.
- W4211022969 cites W1591586904 @default.
- W4211022969 cites W1963911499 @default.
- W4211022969 cites W1966865050 @default.
- W4211022969 cites W1970080655 @default.
- W4211022969 cites W1974743214 @default.
- W4211022969 cites W1974871997 @default.
- W4211022969 cites W1975262077 @default.
- W4211022969 cites W1976883040 @default.
- W4211022969 cites W1980196573 @default.
- W4211022969 cites W1981904009 @default.
- W4211022969 cites W1982549153 @default.
- W4211022969 cites W1986409845 @default.
- W4211022969 cites W1988924363 @default.
- W4211022969 cites W1990871033 @default.
- W4211022969 cites W1990962975 @default.
- W4211022969 cites W1992681681 @default.
- W4211022969 cites W1993358972 @default.
- W4211022969 cites W1995274436 @default.
- W4211022969 cites W1997463606 @default.
- W4211022969 cites W2000078853 @default.
- W4211022969 cites W2001144407 @default.
- W4211022969 cites W2001757227 @default.
- W4211022969 cites W2003324717 @default.
- W4211022969 cites W2003527639 @default.
- W4211022969 cites W2011043234 @default.
- W4211022969 cites W2011719641 @default.
- W4211022969 cites W2011865872 @default.
- W4211022969 cites W2012030506 @default.
- W4211022969 cites W2020271347 @default.
- W4211022969 cites W2022075976 @default.
- W4211022969 cites W2022499434 @default.
- W4211022969 cites W2023911289 @default.
- W4211022969 cites W2025566426 @default.
- W4211022969 cites W2027707345 @default.
- W4211022969 cites W2028792610 @default.
- W4211022969 cites W2035492280 @default.
- W4211022969 cites W2035756199 @default.
- W4211022969 cites W2037487590 @default.
- W4211022969 cites W2038451255 @default.
- W4211022969 cites W2039134848 @default.
- W4211022969 cites W2039552575 @default.
- W4211022969 cites W2039742719 @default.
- W4211022969 cites W2041278780 @default.
- W4211022969 cites W2042773228 @default.
- W4211022969 cites W2044699218 @default.
- W4211022969 cites W2046698603 @default.
- W4211022969 cites W2059431839 @default.
- W4211022969 cites W2059652945 @default.
- W4211022969 cites W2060163624 @default.
- W4211022969 cites W2060980599 @default.
- W4211022969 cites W2061248632 @default.
- W4211022969 cites W2061586430 @default.
- W4211022969 cites W2062534239 @default.
- W4211022969 cites W2063132311 @default.
- W4211022969 cites W2064213620 @default.
- W4211022969 cites W2065896216 @default.
- W4211022969 cites W2066078737 @default.
- W4211022969 cites W2066118588 @default.
- W4211022969 cites W2067088166 @default.
- W4211022969 cites W2071059291 @default.
- W4211022969 cites W2076715063 @default.
- W4211022969 cites W2076940625 @default.
- W4211022969 cites W2080925759 @default.
- W4211022969 cites W2081201396 @default.
- W4211022969 cites W2085472041 @default.
- W4211022969 cites W2086902980 @default.
- W4211022969 cites W2088628989 @default.
- W4211022969 cites W2089176522 @default.
- W4211022969 cites W2091231154 @default.
- W4211022969 cites W2092466460 @default.
- W4211022969 cites W2093448331 @default.
- W4211022969 cites W2098740155 @default.
- W4211022969 cites W2115782706 @default.
- W4211022969 cites W2116860923 @default.
- W4211022969 cites W2126979837 @default.
- W4211022969 cites W2146080161 @default.
- W4211022969 cites W2160316096 @default.
- W4211022969 cites W2166295771 @default.
- W4211022969 cites W2167624291 @default.
- W4211022969 cites W2331023644 @default.
- W4211022969 cites W4236682081 @default.
- W4211022969 cites W4238400795 @default.
- W4211022969 cites W4247272913 @default.
- W4211022969 doi "https://doi.org/10.1016/0378-3812(94)80003-0" @default.
- W4211022969 hasPublicationYear "1994" @default.
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