Matches in SemOpenAlex for { <https://semopenalex.org/work/W4211036229> ?p ?o ?g. }
- W4211036229 endingPage "4795" @default.
- W4211036229 startingPage "4783" @default.
- W4211036229 abstract "In this article, three new zinc(II) coordination polymers have been synthesized using 4,4′-azobipyridine (azbpy) and three different aliphatic dicarboxylates. The reaction was carried out through the slow diffusion technique at room temperature giving rise to {[Zn2(μ3-OH)(azbpy) (suc)1.5]·(H2O)2}n (1), {[Zn(azbpy)0.5(glut)(H2O)]·(H2O)}n (2), and {[Zn2(azbpy)2(fum)2]·(H2O)}n (3) (suc = succinate dianion, glut = glutarate dianion and fum = fumarate dianion). The structures of these complexes were determined by single-crystal X-ray diffraction analysis and also by other physicochemical methods. Compound 1 is a three-dimensional (3D) framework, whereas compound 2 shows a one-dimensional ladder-like structure which is further extended in two dimensions through supramolecular interactions (H-bonding). Compound 3 displays a three-dimensional (3D) 5-fold interpenetrated diamondoid network structure. In the case of 1 and 2, the structures contain void spaces which are occupied by guest water molecules, whereas in 3, the pores are totally blocked through interpenetration. TGA and PXRD analysis showed that all three compounds were thermally stable up to a high temperature. The desolvated framework of compounds 1 and 2 show adsorption of different gas molecules and exhibit a higher adsorption preference for CO2 over N2. The photoluminescence study in the solid state of compounds 1–3 indicates ligand based florescence emissions at room temperature." @default.
- W4211036229 created "2022-02-13" @default.
- W4211036229 creator A5002512288 @default.
- W4211036229 creator A5042246095 @default.
- W4211036229 creator A5057138590 @default.
- W4211036229 creator A5057222945 @default.
- W4211036229 creator A5078661934 @default.
- W4211036229 date "2014-01-01" @default.
- W4211036229 modified "2023-10-16" @default.
- W4211036229 title "Syntheses, X-ray structures, gas adsorption and luminescent properties of three coordination polymers of Zn(<scp>ii</scp>) dicarboxylates mixed with a linear, neutral, and rigid N,N′-donor ligand" @default.
- W4211036229 cites W1963505948 @default.
- W4211036229 cites W1966535971 @default.
- W4211036229 cites W1967109824 @default.
- W4211036229 cites W1967148466 @default.
- W4211036229 cites W1967585041 @default.
- W4211036229 cites W1968000110 @default.
- W4211036229 cites W1972646318 @default.
- W4211036229 cites W1975355237 @default.
- W4211036229 cites W1980147427 @default.
- W4211036229 cites W1981466385 @default.
- W4211036229 cites W1981970530 @default.
- W4211036229 cites W1985148570 @default.
- W4211036229 cites W1985290478 @default.
- W4211036229 cites W1987196386 @default.
- W4211036229 cites W1987445022 @default.
- W4211036229 cites W1989118706 @default.
- W4211036229 cites W1992545229 @default.
- W4211036229 cites W1994043450 @default.
- W4211036229 cites W1996369650 @default.
- W4211036229 cites W1997813480 @default.
- W4211036229 cites W1999908724 @default.
- W4211036229 cites W1999937609 @default.
- W4211036229 cites W2004364435 @default.
- W4211036229 cites W2004550299 @default.
- W4211036229 cites W2007548657 @default.
- W4211036229 cites W2007661885 @default.
- W4211036229 cites W2010501742 @default.
- W4211036229 cites W2010637586 @default.
- W4211036229 cites W2010815720 @default.
- W4211036229 cites W2011018859 @default.
- W4211036229 cites W2011879584 @default.
- W4211036229 cites W2012133724 @default.
- W4211036229 cites W2015428601 @default.
- W4211036229 cites W2015887679 @default.
- W4211036229 cites W2017226414 @default.
- W4211036229 cites W2030951057 @default.
- W4211036229 cites W2031476977 @default.
- W4211036229 cites W2031792068 @default.
- W4211036229 cites W2038846202 @default.
- W4211036229 cites W2039473171 @default.
- W4211036229 cites W2040436359 @default.
- W4211036229 cites W2041816676 @default.
- W4211036229 cites W2042397184 @default.
- W4211036229 cites W2043431594 @default.
- W4211036229 cites W2044235192 @default.
- W4211036229 cites W2044491102 @default.
- W4211036229 cites W2045258228 @default.
- W4211036229 cites W2045694684 @default.
- W4211036229 cites W2047725841 @default.
- W4211036229 cites W2049021182 @default.
- W4211036229 cites W2049457092 @default.
- W4211036229 cites W2050081991 @default.
- W4211036229 cites W2056259200 @default.
- W4211036229 cites W2059020082 @default.
- W4211036229 cites W2059665237 @default.
- W4211036229 cites W2062269633 @default.
- W4211036229 cites W2063334178 @default.
- W4211036229 cites W2064093334 @default.
- W4211036229 cites W2065493972 @default.
- W4211036229 cites W2066784675 @default.
- W4211036229 cites W2070132142 @default.
- W4211036229 cites W2071020704 @default.
- W4211036229 cites W2071944159 @default.
- W4211036229 cites W2072039234 @default.
- W4211036229 cites W2074260935 @default.
- W4211036229 cites W2076460374 @default.
- W4211036229 cites W2077262548 @default.
- W4211036229 cites W2081048748 @default.
- W4211036229 cites W2085418823 @default.
- W4211036229 cites W2087359709 @default.
- W4211036229 cites W2089848237 @default.
- W4211036229 cites W2090532065 @default.
- W4211036229 cites W2091274227 @default.
- W4211036229 cites W2094005838 @default.
- W4211036229 cites W2094145140 @default.
- W4211036229 cites W2098292174 @default.
- W4211036229 cites W2099851263 @default.
- W4211036229 cites W2101187042 @default.
- W4211036229 cites W2101421043 @default.
- W4211036229 cites W2102830904 @default.
- W4211036229 cites W2105229123 @default.
- W4211036229 cites W2105249240 @default.
- W4211036229 cites W2106280766 @default.
- W4211036229 cites W2108606629 @default.
- W4211036229 cites W2112358649 @default.
- W4211036229 cites W2113763565 @default.
- W4211036229 cites W2114157047 @default.
- W4211036229 cites W2114784691 @default.