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- W4211054090 abstract "It is very important to find cheap and efficient catalysts for catalytic co-pyrolysis. Catalytic co-pyrolysis of herb residue (HR) and reused polypropylene (PP) using Ni-X/biochar and ZSM-5 (X = Fe, Co, Cu) was performed to produce pyrolysis oil, pyrolysis gas and carbon nanotubes (CNTs) in a two-stage fixed bed reactor. Bimetallic biochar catalysts exhibited higher catalytic activity due to their higher specific surface area (SBET) and more strong acid sites. NiCu/biochar significantly increased the yield of pyrolysis oil by enhancing Fischer-Tropsch synthesis. In addition, the stronger secondary cracking capacity of NiCu/biochar resulted in the highest content of hydrocarbons (80.47%) and C6-C11(61.10%), while the availability of higher content of carbon source gas also facilitated the formation of CNTs and H2 at back-end. The cheap and efficient NiCu/biochar catalyst has great potential in the application of catalytic pyrolysis, which is conducive to the large-scale promotion of biomass pyrolysis technology." @default.
- W4211054090 created "2022-02-13" @default.
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- W4211054090 date "2022-04-01" @default.
- W4211054090 modified "2023-10-14" @default.
- W4211054090 title "Catalytic co-pyrolysis of herb residue and polypropylene for pyrolysis products upgrading and diversification using nickel-X/biochar and ZSM-5 (X = iron, cobalt, copper)" @default.
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- W4211054090 doi "https://doi.org/10.1016/j.biortech.2022.126845" @default.
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