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• W4211059488 abstract "A Ru-catalyzed direct oxidative coupling reaction of vinyl ketones was developed. It offers a straightforward and atom-economical protocol for the synthesis of functionalized (E,E)-1,6-dioxo-2,4-diene derivatives in moderate to good yields with excellent stereo- and chemoselectivities. In addition, the synthetic utility of this method was further demonstrated by its application to the synthesis of bioactive natural products such as (7E,9E)-henicosa-7,9-diene-6,11-dione (sex pheromone), ostopanic acid (plant anticancer agent), JA (anti-tumor agent) and the southern part (C1-C13) of the antibiotic macrolactin-T." @default.
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• W4211059488 date "2022-01-01" @default.
• W4211059488 modified "2023-09-27" @default.
• W4211059488 title "Ruthenium-catalyzed stereo- and chemoselective oxidative coupling of vinyl ketones: efficient access to (<i>E</i>,<i>E</i>)-1,6-dioxo-2,4-dienes" @default.
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• W4211059488 doi "https://doi.org/10.1039/d1cc06680c" @default.
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