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- W4211075570 endingPage "104258" @default.
- W4211075570 startingPage "104258" @default.
- W4211075570 abstract "Despite the exciting activities of organoselenium compounds, their anticorrosive efficiency was scarcely valued in the literature. Herein, two novel organoselenium-based N-mealanilic acids Namely: (E)-4-((2-(methoxycarbonyl)-4-selenocyanatophenyl)amino)-4-oxobut-2-enoic acid (NMSeCN) and (2E,2′E)-4,4′-((diselanediylbis(2-(methoxycarbonyl)-4,1-phenylene))bis(azanediyl))bis(4-oxobut-2-enoic acid) (NMSe2) were synthesized. Their corrosion inhibition was examined towards 6061 aluminum alloy in 1.0 mol L − 1 HCl utilizing potentiodynamic polarization (PP), impedance spectroscopy (EIS), Energy-dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), Density Functional Theory (DFT), and Monte Carlo (MC) simulations. Electrochemical findings revealed the inhibition efficiency enhance in the order: NMSe2 > NMSeCN with extreme protection efficacy (98.2%) obtained at 6.4 × 10−3 mol L − 1 of NMSe2. Both cathodic (βc) and anodic (βa) Tafel constants were appreciably influenced by the insertion of the additives into the corrosion solution suggesting a mixed type reduces both anodic and cathodic reaction. The adsorption of the NMSeCN and NMSe2 on the aluminum surface is spontaneous and followed the isotherm of Langmuir. The annealing adsorption simulations showed a nearly flat configuration of NMSeCN and NMSe2 molecules on Al (1 1 1) surface which endorses optimal surface coverage. DFT calculations showed that the donation ability of NMSe2 inhibitor to the Al alloy interface is higher than the NMSeCN which in turn was in good agreement with the electrochemical experiments. According to the experimental and theoretical outcomes, the inhibition mechanism was suggested." @default.
- W4211075570 created "2022-02-13" @default.
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- W4211075570 date "2022-04-01" @default.
- W4211075570 modified "2023-09-24" @default.
- W4211075570 title "Novel organoselenium-based N-mealanilic acids as efficacious corrosion inhibitors for 6061 aluminum alloy in molar HCl: In-silico modeling, electrochemical, and surface morphology studies" @default.
- W4211075570 cites W1033343317 @default.
- W4211075570 cites W1537929654 @default.
- W4211075570 cites W181325238 @default.
- W4211075570 cites W1976525951 @default.
- W4211075570 cites W1980653386 @default.
- W4211075570 cites W1988078840 @default.
- W4211075570 cites W1999044006 @default.
- W4211075570 cites W2001650409 @default.
- W4211075570 cites W2011012616 @default.
- W4211075570 cites W2011286463 @default.
- W4211075570 cites W2014947339 @default.
- W4211075570 cites W2022309069 @default.
- W4211075570 cites W2022843694 @default.
- W4211075570 cites W2023567383 @default.
- W4211075570 cites W2032969358 @default.
- W4211075570 cites W2042838992 @default.
- W4211075570 cites W2046703754 @default.
- W4211075570 cites W2049070753 @default.
- W4211075570 cites W2050316854 @default.
- W4211075570 cites W2058289127 @default.
- W4211075570 cites W2061063426 @default.
- W4211075570 cites W2074719032 @default.
- W4211075570 cites W2077223069 @default.
- W4211075570 cites W2080345499 @default.
- W4211075570 cites W2082177272 @default.
- W4211075570 cites W2086708818 @default.
- W4211075570 cites W2086738977 @default.
- W4211075570 cites W2088864171 @default.
- W4211075570 cites W2089250048 @default.
- W4211075570 cites W2091464399 @default.
- W4211075570 cites W2100170791 @default.
- W4211075570 cites W2184487589 @default.
- W4211075570 cites W2275509285 @default.
- W4211075570 cites W2278790185 @default.
- W4211075570 cites W2293161107 @default.
- W4211075570 cites W2321273681 @default.
- W4211075570 cites W2374520012 @default.
- W4211075570 cites W2411479549 @default.
- W4211075570 cites W2507138303 @default.
- W4211075570 cites W2514243758 @default.
- W4211075570 cites W2559397032 @default.
- W4211075570 cites W2585610101 @default.
- W4211075570 cites W2783769572 @default.
- W4211075570 cites W2792912819 @default.
- W4211075570 cites W2800799439 @default.
- W4211075570 cites W2803898231 @default.
- W4211075570 cites W2804392642 @default.
- W4211075570 cites W2805960976 @default.
- W4211075570 cites W2913587980 @default.
- W4211075570 cites W2919153475 @default.
- W4211075570 cites W2934737162 @default.
- W4211075570 cites W2943126041 @default.
- W4211075570 cites W2954367772 @default.
- W4211075570 cites W2955569956 @default.
- W4211075570 cites W2957055056 @default.
- W4211075570 cites W2965993899 @default.
- W4211075570 cites W2969208044 @default.
- W4211075570 cites W2971737261 @default.
- W4211075570 cites W2979966570 @default.
- W4211075570 cites W2989976778 @default.
- W4211075570 cites W2995337974 @default.
- W4211075570 cites W3004844835 @default.
- W4211075570 cites W3011715950 @default.
- W4211075570 cites W3021231379 @default.
- W4211075570 cites W3037220014 @default.
- W4211075570 cites W3040285276 @default.
- W4211075570 cites W3044804994 @default.
- W4211075570 cites W3089046365 @default.
- W4211075570 cites W3092760379 @default.
- W4211075570 cites W3094270023 @default.
- W4211075570 cites W3094636894 @default.
- W4211075570 cites W3096847092 @default.
- W4211075570 cites W3119757965 @default.
- W4211075570 cites W3127764735 @default.
- W4211075570 cites W3130420937 @default.
- W4211075570 cites W3136109172 @default.
- W4211075570 cites W3157107783 @default.
- W4211075570 cites W3164370663 @default.
- W4211075570 cites W3165940744 @default.
- W4211075570 cites W3193910468 @default.
- W4211075570 cites W3198319118 @default.
- W4211075570 doi "https://doi.org/10.1016/j.jtice.2022.104258" @default.
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