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- W4211084975 abstract "Abstract An overview of polyphosphazene science is given. A brief history of over 100 years of synthetic developments is presented, from the work of Stokes to the latest cationic condensation polymerization, followed by discussions of blending, cross‐linking, and functionalization. Applications of polyphosphazenes as elastomers, solid polymer electrolytes, membranes, and flame retardants are reviewed. Biomedical research is referenced and hybrid polyphosphazenes and polymers containing cyclophosphazenes are also covered briefly. Although the limitless derivatization possibilities along with the attractiveness of the inorganic P–N backbone has generated enormous scientific interest in polyphosphazenes, current synthetic routes are characterized by high costs of the substrates, high instability of the intermediate polydichlorophosphazene, and sensitivity of the resultant polyphosphazene to the synthesis conditions. The need for costly process equipment must also be taken into account when assessing the cost of synthesizing polyphosphazenes on a commercial scale. Initial manufacturing efforts by Firestone, Ethyl Corporation, and Elf Atochem were terminated, but various polyphosphazene derivatives are available from custom synthesis companies. Therefore, polyphosphazenes should be considered still under the development stage." @default.
- W4211084975 created "2022-02-13" @default.
- W4211084975 creator A5017174420 @default.
- W4211084975 creator A5070922218 @default.
- W4211084975 date "2003-04-15" @default.
- W4211084975 modified "2023-10-14" @default.
- W4211084975 title "Polyphosphazenes" @default.
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