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• W4211088097 endingPage "509" @default.
• W4211088097 startingPage "313" @default.
• W4211088097 abstract "Several dinuclear arsenic bridged carbonyl complexes with FeFe, MnCo, and mainly feCo bonds catalyse the dimerization of norbornadiene. The reactions can be directed exclusively to the exo-trans-exo or the Binor-S dimer. In two cases catalytically active intermediates could be isolated. Of these (CO)4Fe-AsMe2-Co(CO)2C7H8 was characterized by an X-ray crystal structure analysis which showed that the norbornadiene molecule has opened the metal metal bond. The catalysts are inactive towards other olefinic substrates.Mehrere zweikernige arsenverbrückte Carbonylkomplexe mit Fe-Fe-, Mn-Co- und hauptsächlich Fe-Co-Bindungen katalysieren die Dimerisation des Norbornadiens. Die Reaktion kann ausschlieBlich zum exo-trans-exo oder dem binor-S-Dimeren gelenkt werden. In zwei Fällen konnten katalytisch aktive Zwischenstufen isoliert werden. Von diesen wurde (CO4Fe-AsMe2-Co(CO)2C7H8 kristallographisch charakterisiert, wobei sich zeigte, daB das Norbornadien-Molekül die Metall-Metall-Bindung geöffnet hat.Die Katalysatoren sind inaktiv gegenüber anderen olefinischen Substraten." @default.
• W4211088097 created "2022-02-13" @default.
• W4211088097 creator A5053013149 @default.
• W4211088097 date "1978-05-01" @default.
• W4211088097 modified "2023-09-27" @default.
• W4211088097 title "Structures of organo-transition metal complexes" @default.
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