FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4211116413> ?p ?o ?g. }

• W4211116413 endingPage "96" @default.
• W4211116413 startingPage "1" @default.
• W4211116413 abstract "This chapter discusses triosmium clusters. Dodecacarbonyltriosmium, OS3 (CO) 12, has been one of the key compounds in the development of transition-metal clusters, because it can undergo a wide range of reactions giving many new clusters, more often than not without any change of nuclearity. Triosmium dodecacarbonyl is the best starting material for triosmium clusters, and hundreds of compounds have now been formed by the reaction of inorganic or organic substrates, directly or more commonly with more reactive derivatives, such as OS3H2(CO)10, Os3(CO)11,L (16–18), or Os3(CO)10 L, (18–21) where L is weakly bound. It is useful to classify compounds so that they may be compared and normal behavior distinguished from the abnormal. This situation is found rarely and is only to be expected when strongly bridging ligands maintain the trinuclear cluster intact. Interest in μ3 ligands lies in the variety of molecules that may be used, in the variation of the number of electrons donated by the bridge, and in the potential, the ligands have to rotate with respect to the three metal atoms. OS3 (CO) 12 was first reported by Hieber as Os2(CO)9 in 1943. The reaction of OsO4 with HI gave an oxyiodide, which was treated with Ag powder in benzene at 150°C under CO (200 atm) to give OS3 (CO)12 in poor yield. Ultraviolet photolysis of OS3 (CO)12 in the presence of dienes, such as butadiene, cyclooctatetraene, or cyclooctadienes leads to the mononuclear species of type Os(CO)3(diene)." @default.
• W4211116413 created "2022-02-13" @default.
• W4211116413 creator A5075360098 @default.
• W4211116413 date "1986-01-01" @default.
• W4211116413 modified "2023-10-16" @default.
• W4211116413 title "Triosmium Clusters" @default.
• W4211116413 cites W1276473719 @default.
• W4211116413 cites W1453713361 @default.
• W4211116413 cites W1482238928 @default.
• W4211116413 cites W1510820267 @default.
• W4211116413 cites W1519189777 @default.
• W4211116413 cites W1533773203 @default.
• W4211116413 cites W1560307230 @default.
• W4211116413 cites W1570779242 @default.
• W4211116413 cites W161046231 @default.
• W4211116413 cites W1963547114 @default.
• W4211116413 cites W1965045726 @default.
• W4211116413 cites W1965618650 @default.
• W4211116413 cites W1965890865 @default.
• W4211116413 cites W1966030288 @default.
• W4211116413 cites W1966670721 @default.
• W4211116413 cites W1966835431 @default.
• W4211116413 cites W1966929595 @default.
• W4211116413 cites W1967066999 @default.
• W4211116413 cites W1969343221 @default.
• W4211116413 cites W1969352169 @default.
• W4211116413 cites W1969358861 @default.
• W4211116413 cites W1970579929 @default.
• W4211116413 cites W1970968534 @default.
• W4211116413 cites W1971661453 @default.
• W4211116413 cites W1971861393 @default.
• W4211116413 cites W1972053661 @default.
• W4211116413 cites W1973075852 @default.
• W4211116413 cites W1973443834 @default.
• W4211116413 cites W1975315354 @default.
• W4211116413 cites W1976029000 @default.
• W4211116413 cites W1976297128 @default.
• W4211116413 cites W197643260 @default.
• W4211116413 cites W1976451239 @default.
• W4211116413 cites W1976984532 @default.
• W4211116413 cites W1977553481 @default.
• W4211116413 cites W1977617858 @default.
• W4211116413 cites W1977735073 @default.
• W4211116413 cites W1977858427 @default.
• W4211116413 cites W1977998148 @default.
• W4211116413 cites W1978703310 @default.
• W4211116413 cites W1978902615 @default.
• W4211116413 cites W1978903975 @default.
• W4211116413 cites W1978974928 @default.
• W4211116413 cites W1978994958 @default.
• W4211116413 cites W1979204456 @default.
• W4211116413 cites W1979216473 @default.
• W4211116413 cites W1979713380 @default.
• W4211116413 cites W1980496557 @default.
• W4211116413 cites W1981331277 @default.
• W4211116413 cites W1981499131 @default.
• W4211116413 cites W1981716676 @default.
• W4211116413 cites W1981748090 @default.
• W4211116413 cites W1982906768 @default.
• W4211116413 cites W1982927654 @default.
• W4211116413 cites W1982964672 @default.
• W4211116413 cites W1983221212 @default.
• W4211116413 cites W1983315492 @default.
• W4211116413 cites W1983406658 @default.
• W4211116413 cites W1983425875 @default.
• W4211116413 cites W1983430628 @default.
• W4211116413 cites W1983726358 @default.
• W4211116413 cites W1983726755 @default.
• W4211116413 cites W1984401311 @default.
• W4211116413 cites W1984446965 @default.
• W4211116413 cites W1984475315 @default.
• W4211116413 cites W1984596124 @default.
• W4211116413 cites W1984872704 @default.
• W4211116413 cites W1985484935 @default.
• W4211116413 cites W1986429770 @default.
• W4211116413 cites W1986752646 @default.
• W4211116413 cites W1986904709 @default.
• W4211116413 cites W1987159376 @default.
• W4211116413 cites W1987972459 @default.
• W4211116413 cites W1988289845 @default.
• W4211116413 cites W1988517900 @default.
• W4211116413 cites W1990052449 @default.
• W4211116413 cites W1990370413 @default.
• W4211116413 cites W1990560092 @default.
• W4211116413 cites W1990905176 @default.
• W4211116413 cites W1991588015 @default.
• W4211116413 cites W1991627325 @default.
• W4211116413 cites W1992158964 @default.
• W4211116413 cites W1992275761 @default.
• W4211116413 cites W1992398185 @default.
• W4211116413 cites W1992425436 @default.
• W4211116413 cites W1992646022 @default.
• W4211116413 cites W1992679845 @default.
• W4211116413 cites W1992876185 @default.
• W4211116413 cites W1993230695 @default.
• W4211116413 cites W1993293409 @default.
• W4211116413 cites W1993464306 @default.
• W4211116413 cites W1993557133 @default.

• next