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• W4211132015 startingPage "100231" @default.
• W4211132015 abstract "Lithium-conducting NASICON materials are frequently researched for their high ionic conductivity and possible application in solid state batteries. The highest ionic conductivities are found for M(III) cation substituted LiTi2(PO4)3 derivates. While aluminum substituted compositions are mostly researched as electrolyte-materials, the chromium and iron containing compounds are mixed conductors and thus suitable materials for cathodes. Conventional synthesis routes of these materials include the highly energy consuming solid-state reaction and the sol-gel method in organic solvents. In this work, the compositions Li1+xM(III)xTi2-x(PO4)3 (M(III) = Al, Cr, Fe; 0.5 ≤ x ≤ 2.0) were synthesized by two rather new synthetic routes in an aqueous solution that requires a reduced number of educts. Stoichiometry, crystal- and microstructure, density and conductivity were investigated. The ionic conductivities of the resulting NASICON-materials are mostly within the range of comparative literature and the applied synthesis methods can be considered as suitable for these compositions." @default.
• W4211132015 created "2022-02-13" @default.
• W4211132015 creator A5009215182 @default.
• W4211132015 creator A5040359883 @default.
• W4211132015 date "2022-03-01" @default.
• W4211132015 modified "2023-09-27" @default.
• W4211132015 title "Preparation, characterization and conductivity of NASICON-type Li1+M(III)Ti2-(PO4)3 (M(III) = Al, Cr, Fe; 0.5 ≤ x ≤ 2.0) materials via modern, scalable synthesis routes" @default.
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• W4211132015 doi "https://doi.org/10.1016/j.oceram.2022.100231" @default.
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