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- W4211142761 abstract "Fission product Ru, normally volatile to the extent of 20 to 60% in evaporation and calcination of simulated high level radioactive wastes at 500 to 1000 deg C, can be 99.9% retained in the solid product by addition of 2 moles of phosphite or hynophosphite per liter of waste. As little as 0.1 mole per liter lowered the Ru volatility during distillation approaching equilibrium by factors which varied from 38 for Darex to 225 for TBP-25 (aluminum) waste solutions. The final products with Purex, TBP-25, and Darex (stainless steel) wastes were insoluble glassy solids with densities of 2.4 to 3.8 g/ml and represented volume reductions of 2.9 to 8. These volume reductions are essentially the same as those obtained when the waste is calcined without additives. (auth)" @default.
- W4211142761 created "2022-02-13" @default.
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- W4211142761 date "1962-06-19" @default.
- W4211142761 modified "2023-10-17" @default.
- W4211142761 title "THE USE OF PHOSPHITE AND HYPOPHOSPHITE TO FIX RUTHENIUM FROM HIGH-ACTIVITY WASTES IN SOLID MEDIA" @default.
- W4211142761 doi "https://doi.org/10.2172/4748316" @default.
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