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- W4211156984 endingPage "18121" @default.
- W4211156984 startingPage "18114" @default.
- W4211156984 abstract "Abstract Triene 6π electrocyclization, wherein a conjugated triene undergoes a concerted stereospecific cycloisomerization to a cyclohexadiene, is a reaction of great historical and practical significance. In order to circumvent limitations imposed by the normally harsh reaction conditions, chemists have long sought to develop catalytic variants based upon the activating power of metal–alkene coordination. Herein, we demonstrate the first successful implementation of such a strategy by utilizing [(C 5 H 5 )Ru(NCMe) 3 ]PF 6 as a precatalyst for the disrotatory 6π electrocyclization of highly substituted trienes that are resistant to thermal cyclization. Mechanistic and computational studies implicate hexahapto transition‐metal coordination as responsible for lowering the energetic barrier to ring closure. This work establishes a foundation for the development of new catalysts for stereoselective electrocyclizations." @default.
- W4211156984 created "2022-02-13" @default.
- W4211156984 creator A5015985705 @default.
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- W4211156984 creator A5045316090 @default.
- W4211156984 creator A5057803757 @default.
- W4211156984 creator A5058557888 @default.
- W4211156984 creator A5067301238 @default.
- W4211156984 date "2020-08-14" @default.
- W4211156984 modified "2023-09-26" @default.
- W4211156984 title "Transition‐Metal Catalysis of Triene 6π Electrocyclization: The π‐Complexation Strategy Realized" @default.
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