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- W4211179695 endingPage "182" @default.
- W4211179695 startingPage "151" @default.
- W4211179695 abstract "This chapter presents unique aspects of the rearrangement with a focus on (1) the production of carbanions under mild conditions, (2) the generation of synthetically valuable enol silyl ethers that are often the products, (3) the potential for incorporation of the Brook rearrangement in tandem and sequential anion relay processes, and (4) the utility of the rearrangement in generating chiral, configurationally stable carbanions. It presents several strategies to generate α-silyl alkoxide. The chapter discusses applications of Brook rearrangements: in the reactions of acylsilanes with nucleophiles; in the reactions triggered by deprotonation of α-silyl alkoxide-silyl alcohols; reactions triggered by addition of silylmetallic reagents; reactions in α-silyalkoxides generated via regioselective α-ring-opening of α,β-epoxysilanes by a nucleophile; and reactions in α-silyalkoxides generated by a base-induced ring opening of α,β-epoxysilanes." @default.
- W4211179695 created "2022-02-13" @default.
- W4211179695 creator A5000149579 @default.
- W4211179695 creator A5042118446 @default.
- W4211179695 date "2015-10-02" @default.
- W4211179695 modified "2023-09-25" @default.
- W4211179695 title "Brook Rearrangement" @default.
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