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- W4211197902 endingPage "5996" @default.
- W4211197902 startingPage "5991" @default.
- W4211197902 abstract "Abstract Asymmetric cyclopropane synthesis currently requires bespoke strategies, methods, substrates, and reagents, even when targeting similar compounds. This approach slows down discovery and limits available chemical space. Introduced herein is a practical and versatile diazocompound and its performance in the first unified asymmetric synthesis of functionalized cyclopropanes. The redox‐active leaving group in this reagent enhances the reactivity and selectivity of geminal carbene transfer. This effect allowed the asymmetric cyclopropanation of various olefins, including unfunctionalized aliphatic alkenes, that enables the three‐step total synthesis of (−)‐dictyopterene A. This unified synthetic approach delivers high enantioselectivities that are independent of the stereoelectronic properties of the functional groups transferred. Our results demonstrate that orthogonally differentiated diazocompounds are viable and advantageous equivalents of single‐carbon chirons." @default.
- W4211197902 created "2022-02-13" @default.
- W4211197902 creator A5019776623 @default.
- W4211197902 creator A5025998074 @default.
- W4211197902 creator A5038914713 @default.
- W4211197902 creator A5049636348 @default.
- W4211197902 creator A5070176665 @default.
- W4211197902 creator A5076034197 @default.
- W4211197902 date "2019-02-15" @default.
- W4211197902 modified "2023-10-14" @default.
- W4211197902 title "General Cyclopropane Assembly by Enantioselective Transfer of a Redox‐Active Carbene to Aliphatic Olefins" @default.
- W4211197902 cites W1964284609 @default.
- W4211197902 cites W1965866555 @default.
- W4211197902 cites W1971879173 @default.
- W4211197902 cites W1976428809 @default.
- W4211197902 cites W1977732935 @default.
- W4211197902 cites W1985011356 @default.
- W4211197902 cites W1995212121 @default.
- W4211197902 cites W2000157693 @default.
- W4211197902 cites W2006290001 @default.
- W4211197902 cites W2007847858 @default.
- W4211197902 cites W2010192832 @default.
- W4211197902 cites W2018208838 @default.
- W4211197902 cites W2019573388 @default.
- W4211197902 cites W2020974687 @default.
- W4211197902 cites W2022303525 @default.
- W4211197902 cites W2023898505 @default.
- W4211197902 cites W2024874069 @default.
- W4211197902 cites W2030717665 @default.
- W4211197902 cites W2048576554 @default.
- W4211197902 cites W2050166845 @default.
- W4211197902 cites W2054473656 @default.
- W4211197902 cites W2063405275 @default.
- W4211197902 cites W2064224186 @default.
- W4211197902 cites W2069993175 @default.
- W4211197902 cites W2075029904 @default.
- W4211197902 cites W2078531329 @default.
- W4211197902 cites W2081478326 @default.
- W4211197902 cites W2089582836 @default.
- W4211197902 cites W2091800127 @default.
- W4211197902 cites W2092379317 @default.
- W4211197902 cites W2095097037 @default.
- W4211197902 cites W2099955759 @default.
- W4211197902 cites W2118638551 @default.
- W4211197902 cites W2118923747 @default.
- W4211197902 cites W2127138447 @default.
- W4211197902 cites W2145296829 @default.
- W4211197902 cites W2147767064 @default.
- W4211197902 cites W2153829659 @default.
- W4211197902 cites W2155629262 @default.
- W4211197902 cites W2170774974 @default.
- W4211197902 cites W2233724884 @default.
- W4211197902 cites W2261087384 @default.
- W4211197902 cites W2315042253 @default.
- W4211197902 cites W2316894931 @default.
- W4211197902 cites W2318115415 @default.
- W4211197902 cites W2324092159 @default.
- W4211197902 cites W2326495393 @default.
- W4211197902 cites W2331824487 @default.
- W4211197902 cites W2336139511 @default.
- W4211197902 cites W2336805901 @default.
- W4211197902 cites W2344238170 @default.
- W4211197902 cites W2407286455 @default.
- W4211197902 cites W2415341105 @default.
- W4211197902 cites W2415371057 @default.
- W4211197902 cites W2422726141 @default.
- W4211197902 cites W2473940512 @default.
- W4211197902 cites W2500710833 @default.
- W4211197902 cites W2512144607 @default.
- W4211197902 cites W2522311304 @default.
- W4211197902 cites W2560605803 @default.
- W4211197902 cites W2561830131 @default.
- W4211197902 cites W2572723913 @default.
- W4211197902 cites W2590733624 @default.
- W4211197902 cites W2591510953 @default.
- W4211197902 cites W2598757999 @default.
- W4211197902 cites W2600461956 @default.
- W4211197902 cites W2602529349 @default.
- W4211197902 cites W2606260360 @default.
- W4211197902 cites W2607693203 @default.
- W4211197902 cites W2611749692 @default.
- W4211197902 cites W2615296728 @default.
- W4211197902 cites W2616515110 @default.
- W4211197902 cites W2625492040 @default.
- W4211197902 cites W2740589262 @default.
- W4211197902 cites W2747641380 @default.
- W4211197902 cites W2749599940 @default.
- W4211197902 cites W2749667268 @default.
- W4211197902 cites W2765308013 @default.
- W4211197902 cites W2766306160 @default.
- W4211197902 cites W2766506930 @default.
- W4211197902 cites W2767046718 @default.
- W4211197902 cites W2773097126 @default.
- W4211197902 cites W2785508050 @default.
- W4211197902 cites W2786747858 @default.
- W4211197902 cites W2790121956 @default.
- W4211197902 cites W2791698034 @default.
- W4211197902 cites W2792018955 @default.