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- W4211209830 endingPage "420" @default.
- W4211209830 startingPage "420" @default.
- W4211209830 abstract "Gas-phase ion chemistry is a useful approach for the investigation of physical organic chemistry and the study of reactivity, structure, and thermochemical properties of ionic and neutral organic substrates. This review summarizes the physical organic chemistry studies utilizing gas-phase ion chemistry reported in the past year. Among the more significant advances reported in the past year included a report of the reactivity of p-benzyne by Kenttämaa and co-workers, a comparison of the SN2 reaction in the gas-phase and in solution by Brauman and co-workers, and a full characterization of the structure and energetics of cyanocarbene. Information learned from these gas-phase ion studies includes: 1) p-benzyne undergoes radical reactions but also reacts as a weak electrophile; 2) unlike what is found in solution, steric bulk does not significantly affect the barriers for SN2 reactions of halogenated nitriles; and 3) HCCN is a “floppy” molecule with a triplet ground state and a singlet excited state that is ca. 50 kJ mol−1 higher in energy." @default.
- W4211209830 created "2022-02-13" @default.
- W4211209830 creator A5042892552 @default.
- W4211209830 creator A5054489541 @default.
- W4211209830 date "2003-01-01" @default.
- W4211209830 modified "2023-10-14" @default.
- W4211209830 title "12 Organic gas-phase ion chemistry" @default.
- W4211209830 cites W1552022326 @default.
- W4211209830 cites W1613395621 @default.
- W4211209830 cites W1639368258 @default.
- W4211209830 cites W1700113750 @default.
- W4211209830 cites W1965780952 @default.
- W4211209830 cites W1972204398 @default.
- W4211209830 cites W1972978306 @default.
- W4211209830 cites W1973042850 @default.
- W4211209830 cites W1973904406 @default.
- W4211209830 cites W1977771851 @default.
- W4211209830 cites W1981641737 @default.
- W4211209830 cites W1982486705 @default.
- W4211209830 cites W1982670161 @default.
- W4211209830 cites W1983038549 @default.
- W4211209830 cites W1983553905 @default.
- W4211209830 cites W1987182008 @default.
- W4211209830 cites W1987409907 @default.
- W4211209830 cites W1987425466 @default.
- W4211209830 cites W1987490013 @default.
- W4211209830 cites W1988536289 @default.
- W4211209830 cites W1988612256 @default.
- W4211209830 cites W1989946284 @default.
- W4211209830 cites W1990234162 @default.
- W4211209830 cites W1991829241 @default.
- W4211209830 cites W1991879412 @default.
- W4211209830 cites W1992174893 @default.
- W4211209830 cites W1992542833 @default.
- W4211209830 cites W1993051169 @default.
- W4211209830 cites W1993510993 @default.
- W4211209830 cites W1996296761 @default.
- W4211209830 cites W1998403826 @default.
- W4211209830 cites W1998862337 @default.
- W4211209830 cites W1998940183 @default.
- W4211209830 cites W1999786517 @default.
- W4211209830 cites W2001531214 @default.
- W4211209830 cites W2001705443 @default.
- W4211209830 cites W2003590098 @default.
- W4211209830 cites W2004388237 @default.
- W4211209830 cites W2006186708 @default.
- W4211209830 cites W2007099488 @default.
- W4211209830 cites W2007109039 @default.
- W4211209830 cites W2007540086 @default.
- W4211209830 cites W2008318184 @default.
- W4211209830 cites W2008851567 @default.
- W4211209830 cites W2008952279 @default.
- W4211209830 cites W2009235487 @default.
- W4211209830 cites W2011415205 @default.
- W4211209830 cites W2013541087 @default.
- W4211209830 cites W2014057621 @default.
- W4211209830 cites W2014178245 @default.
- W4211209830 cites W2014372869 @default.
- W4211209830 cites W2018203121 @default.
- W4211209830 cites W2018351038 @default.
- W4211209830 cites W2019296784 @default.
- W4211209830 cites W2019972107 @default.
- W4211209830 cites W2020135120 @default.
- W4211209830 cites W2020333562 @default.
- W4211209830 cites W2020985507 @default.
- W4211209830 cites W2021105415 @default.
- W4211209830 cites W2021136863 @default.
- W4211209830 cites W2023521879 @default.
- W4211209830 cites W2023654077 @default.
- W4211209830 cites W2024447593 @default.
- W4211209830 cites W2024937237 @default.
- W4211209830 cites W2028457652 @default.
- W4211209830 cites W2028503523 @default.
- W4211209830 cites W2030146495 @default.
- W4211209830 cites W2030881037 @default.
- W4211209830 cites W2032339598 @default.
- W4211209830 cites W2032955221 @default.
- W4211209830 cites W2035454252 @default.
- W4211209830 cites W2037605679 @default.
- W4211209830 cites W2037718692 @default.
- W4211209830 cites W2038113893 @default.
- W4211209830 cites W2038827073 @default.
- W4211209830 cites W2041674615 @default.
- W4211209830 cites W2044159073 @default.
- W4211209830 cites W2044719522 @default.
- W4211209830 cites W2045235005 @default.
- W4211209830 cites W2048193862 @default.
- W4211209830 cites W2049350309 @default.
- W4211209830 cites W2052061161 @default.
- W4211209830 cites W2053079484 @default.
- W4211209830 cites W2053283523 @default.
- W4211209830 cites W2053843487 @default.
- W4211209830 cites W2053911156 @default.
- W4211209830 cites W2054637871 @default.
- W4211209830 cites W2056685049 @default.
- W4211209830 cites W2057645509 @default.
- W4211209830 cites W2058152719 @default.
- W4211209830 cites W2058269506 @default.