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- W421123460 abstract "The comparative catalytic activities of a few chiral rhodium carboxylato complexes in combination with chiral and achiral phosphines are described. In the hydrogenation of α-acetamidocinnamic acid and its methyl ester, differences are observed in turnover numbers and enantioselectivities. Diastereomeric interactions between chiral carboxylato and chiral phosphine moieties resulting in different rates are clearly seen. Arrhenius plots of (+) and (-) DIOP [DIOP = 2,3 isopropylidene 2,3 dihydroxy-1,4bis (diphenylphosphino) butane] with rhodium (-) mandalato complex give markedly different activation energies." @default.
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- W421123460 date "1994-08-01" @default.
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- W421123460 title "Chiral rhodium carboxylates as asymmetric hydrogenation catalysts" @default.
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- W421123460 doi "https://doi.org/10.1007/bf02843280" @default.
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