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• W4211246475 abstract "Designing of thermally activated delayed fluorescence (TADF) compounds with short TADF decay time and high emission quantum yield is a challenge. This chapter introduces different parameters that have to be addressed for designing efficient TADF materials based on Cu(I) and Ag(I) complexes, and presents case studies of Cu(I) complexes with large and small energy separation, respectively. It discusses the effects of SOC with respect to properties of the lowest triplet state, such as phosphorescence allowedness and zero-field splitting (ZFS). The chapter presents photophysical properties of a new TADF class of Ag(I) complexes, and shows how an extraordinarily efficient TADF material can be designed. The TADF material design is based on photophysical properties investigated for a large number of compounds, in particular, with respect to OLED applications. An equivalent design strategy as developed for the organic materials could also be successful for organometallic TADF materials in future." @default.
• W4211246475 created "2022-02-13" @default.
• W4211246475 creator A5021962724 @default.
• W4211246475 creator A5049427815 @default.
• W4211246475 creator A5077800695 @default.
• W4211246475 creator A5081466018 @default.
• W4211246475 date "2018-10-05" @default.
• W4211246475 modified "2023-10-01" @default.
• W4211246475 title "TADF Material Design: Photophysical Background and Case Studies Focusing on Cu(I) and Ag(I) Complexes^a" @default.
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