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- W4212776157 abstract "Six new phthalan derivatives cytorhizophins D-I (1-6) as well as three known derivatives cytorhizophin C, pestacin and rhizophol B were isolated from Cytospora rhizophorae. Among them, cytorhizophins D-E (1-2) and F-G (3-4) were two pairs of diastereoisomers, all of them featuring a 1-phenyl-1,3-dihydroisobenzofuran scaffold with a highly oxygenated O -linked isopentenyl unit. Besides, cytorhizophins H-I (5-6) represent the first examples of phthalide family with fascinating 6/6/6/5 tetracyclic ring system fusing as unprecedented furo [4,3,2- kl ]xanthen-2 (10b H )-one skeleton. The structures of the new phthalan derivatives were extensively confirmed by detail spectroscopic analysis. The partial absolute configurations of compounds 1-6 were established through electronic circular dichroism (ECD) calculations. Moreover, compounds 1-4 showed remarkable antioxidant activities with EC 50 values ranging from 5.86 to 26.80 μM, which were better than or comparable to that of ascorbic acid (positive control)." @default.
- W4212776157 created "2022-02-24" @default.
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- W4212776157 date "2022-02-14" @default.
- W4212776157 modified "2023-09-25" @default.
- W4212776157 title "Antioxidant Aryl-Substituted Phthalan Derivatives Produced by Endophytic Fungus Cytospora rhizophorae" @default.
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- W4212776157 doi "https://doi.org/10.3389/fchem.2022.826615" @default.
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