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- W4212797908 abstract "As recognized in the early 1960s, catenanes composed of two achiral rings that are oriented (Cnh symmetry) as a result of the sequence of atoms they contain are topologically chiral. Here we present the first synthesis of a highly enantioenriched catenane containing a related but overlooked “co-conformationally ‘topologically’ chiral” stereogenic unit, which arises when a bilaterally symmetric Cnv ring is desymmetrised by the position of an oriented macrocycle." @default.
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- W4212797908 date "2022-02-22" @default.
- W4212797908 modified "2023-09-26" @default.
- W4212797908 title "A Co-conformationally “Topologically” Chiral Catenane" @default.
- W4212797908 doi "https://doi.org/10.26434/chemrxiv-2022-gn5fm" @default.
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