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- W4212823194 abstract "A porous metal-organic framework (MOF) material that sucks up record amounts of xenon and krypton could offer an energy-efficient way to capture those gases during nuclear waste processing ( Angew. Chem., Int. Ed. 2022, DOI: 10.1002/anie.202117807 ). Traces of radioactive xenon and krypton contaminate oxygen, nitrogen, and other gases released during nuclear reprocessing. Expensive cryogenic distillation is typically used to remove these isotopes and ensure they don’t escape into the environment. Researchers now have found that a MOF identified 20 years ago ( J. Am. Chem. Soc. 2000, DOI: 10.1021/ja003159k ) can grab more xenon and krypton than other porous materials. The MOF is a lattice of copper ions connected by adamantane tetracarboxylate ligands. Its pores are lined with C–H groups that preferentially bind the two noble gases, and some of them can shrink to fit perfectly around the gas atoms, says team member Shengqian Ma of the University of" @default.
- W4212823194 created "2022-02-24" @default.
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- W4212823194 date "2022-02-14" @default.
- W4212823194 modified "2023-09-27" @default.
- W4212823194 title "MOF catches Xe and Kr" @default.
- W4212823194 doi "https://doi.org/10.1021/cen-10006-scicon3" @default.
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