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- W4212851804 abstract "<div> <div> <div> <p>Self-immolative linkers offer efficient mechanisms for deprotecting ‘caged’ functional groups in response to specific stimuli. Herein we describe a convenient ‘click’ chemistry method for introducing pendant self-immolative linkers to a polymer backbone through post-polymerization modification. The intro duced triazole rings serve both to anchor the stimuli-cleavable trigger groups to the polymer backbone, while also forming a functional part of the self-immolation cascade. We investigate the polymerization kinetics, post-synthetic modification, and self-immolation mechanism of a model polymer system, and discuss avenues for future studies on poly-pendant self-immolative triazoles as a modular, stimuli-responsive macromolecule platform. </p> </div> </div> </div>" @default.
- W4212851804 created "2022-02-24" @default.
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- W4212851804 date "2021-01-04" @default.
- W4212851804 modified "2023-09-26" @default.
- W4212851804 title "Post-Synthetic ‘Click’ Synthesis of RAFT Polymers with Pendant Self-Immolative Triazoles" @default.
- W4212851804 doi "https://doi.org/10.26434/chemrxiv.13507446.v1" @default.
- W4212851804 hasPublicationYear "2021" @default.
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