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• W4212911442 startingPage "26442" @default.
• W4212911442 abstract "Abstract An unprecedented and general hydroboration of alkenes with BX 3 (X=Br, Cl) as the boration reagent in the presence of i Pr 2 NEt is reported. The addition of i Pr 2 NEt not only suppresses alkene polymerization and haloboration side reactions but also provides an “H” source for hydroboration. More importantly, the site‐fixed installation of a boryl group at the original position of the internal double bond is readily achieved in contrast to conventional transition‐metal‐catalyzed hydroboration processes. Further application to the synthesis of 1, n ‐diborylalkanes ( n =3–10) is also demonstrated. Preliminary mechanistic studies reveal a major reaction pathway that involves radical species and operates through a frustrated Lewis pair type single‐electron‐transfer mechanism." @default.
• W4212911442 created "2022-02-24" @default.
• W4212911442 creator A5004075655 @default.
• W4212911442 creator A5022898608 @default.
• W4212911442 creator A5025143275 @default.
• W4212911442 creator A5067690677 @default.
• W4212911442 creator A5083371477 @default.
• W4212911442 creator A5084886635 @default.
• W4212911442 date "2021-11-05" @default.
• W4212911442 modified "2023-10-01" @default.
• W4212911442 title "Site‐Fixed Hydroboration of Terminal and Internal Alkenes using BX ₃ / ^<i>i</i> Pr ₂ NEt**" @default.
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