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- W4212912954 abstract "A visible-light-promoted aerobic oxyphosphorylation of α-diazoesters and H-phosphine oxides has been developed. Using air as the oxygen source, the reaction proceeded smoothly at room temperature under blue-light irradiation. The α-diazoesters, molecular oxygen, and H-phosphine oxides are conveniently incorporated into a C-O-P(O) unit in one step. The preliminary mechanistic studies indicated that a light-triggered radical process is involved. The developed strategy shows the unrevealed reactivity of diazo compounds with H-phosphine oxides and has potential value in synthetic applications." @default.
- W4212912954 created "2022-02-24" @default.
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- W4212912954 date "2022-02-14" @default.
- W4212912954 modified "2023-10-18" @default.
- W4212912954 title "Visible-Light-Promoted Aerobic Oxyphosphorylation of α-Diazoesters with H-Phosphine Oxides" @default.
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- W4212912954 doi "https://doi.org/10.1021/acs.orglett.2c00198" @default.
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